Highly enantioselective synthesis of organic compound using right- and left-handed helical silica

被引：115
|
作者：
Sato, I
Kadowaki, K
Urabe, H
Jung, JH
Ono, Y
Shinkai, S
Soai, K [1 ]
机构：
[1] Tokyo Univ Sci, Dept Appl Chem, Fac Sci, Shinjuku Ku, Tokyo 1628601, Japan
[2] JST, Chemotransfigurat Project, Kurume, Fukuoka 8390861, Japan
来源：
TETRAHEDRON LETTERS | 2003年 / 44卷 / 04期
关键词：
asymmetric induction; asymmetric synthesis; addition reactions; asymmetric autocatalysis; silica;
D O I：
10.1016/S0040-4039(02)02707-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Highly enantiomerically enriched (up to 96-97% ee) 5-pyrimidyl alkanol was obtained by the addition of diisopropylzinc to pyrimidine-5-carbaldehyde in the presence of the artificially designed chiral inorganic material, right- and left-handed helical silica. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：721 / 724
页数：4
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