Highly enantioselective synthesis of organic compound using right- and left-handed helical silica

被引：115
|
作者：
Sato, I
Kadowaki, K
Urabe, H
Jung, JH
Ono, Y
Shinkai, S
Soai, K [1 ]
机构：
[1] Tokyo Univ Sci, Dept Appl Chem, Fac Sci, Shinjuku Ku, Tokyo 1628601, Japan
[2] JST, Chemotransfigurat Project, Kurume, Fukuoka 8390861, Japan
来源：
TETRAHEDRON LETTERS | 2003年 / 44卷 / 04期
关键词：
asymmetric induction; asymmetric synthesis; addition reactions; asymmetric autocatalysis; silica;
D O I：
10.1016/S0040-4039(02)02707-7
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Highly enantiomerically enriched (up to 96-97% ee) 5-pyrimidyl alkanol was obtained by the addition of diisopropylzinc to pyrimidine-5-carbaldehyde in the presence of the artificially designed chiral inorganic material, right- and left-handed helical silica. (C) 2003 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：721 / 724
页数：4
相关论文
共 50 条
  • [31] Helix-Sense-Selective Synthesis of Right- and Left-Handed Helical Luminescent Poly(diphenylacetylene)s with Memory of the Macromolecular Helicity and Their Helical Structures
    Maeda, Katsuhiro
    Nozaki, Mai
    Hashimoto, Kengo
    Shimomura, Kouhei
    Hirose, Daisuke
    Nishimura, Tatsuya
    Watanabe, Go
    Yashima, Eiji
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2020, 142 (16) : 7668 - 7682
  • [32] Differences between right- and left-femoral bone mineral densities in right- and left-handed men and women
    Dane, S
    Akar, S
    Hacibeyoglu, I
    Varoglu, E
    INTERNATIONAL JOURNAL OF NEUROSCIENCE, 2001, 111 (3-4) : 187 - 192
  • [33] High-efficiency rectifier using composite right-/left-handed transmission line
    Choi, S.
    Lim, S.
    ELECTRONICS LETTERS, 2013, 49 (23) : 1473 - 1474
  • [34] Quadrature VCO Using the Composite Right-/Left-Handed Dual-Resonance Resonator
    Jang, Sheng-Lyang
    Teng, Heng-Fa
    Chang, Chia-Wei
    Hsieh, Chao-Wei
    2012 ASIA-PACIFIC MICROWAVE CONFERENCE (APMC 2012), 2012, : 1223 - 1225
  • [35] Compact broadband 180° Wilkinson divider using right- and left-handed transmission lines
    Jung, S.
    Kim, M.
    Kim, H.
    Park, H.
    Yang, Y.
    IET MICROWAVES ANTENNAS & PROPAGATION, 2010, 4 (12) : 2050 - 2056
  • [36] Revisiting composite right-/left-handed transmission lines and symmetric couplers
    Honarbakhsh, B.
    SCIENTIA IRANICA, 2023, 30 (03) : 1139 - 1147
  • [37] A PITD algorithm for analyzing composite right-/left-handed transmission line
    Chen, Faxiang
    MICROWAVE AND OPTICAL TECHNOLOGY LETTERS, 2024, 66 (01)
  • [38] On the radiation characteristics of right- and left-handed microstrip patch antenna designs
    Fladie, Joshua A.
    Bernhard, Jennifer T.
    IEEE ANTENNAS AND WIRELESS PROPAGATION LETTERS, 2006, 5 : 563 - 565
  • [39] Illusory movements induced by tendon vibration in right- and left-handed people
    Tidoni, Emmanuele
    Fusco, Gabriele
    Leonardis, Daniele
    Frisoli, Antonio
    Bergamasco, Massimo
    Aglioti, Salvatore Maria
    EXPERIMENTAL BRAIN RESEARCH, 2015, 233 (02) : 375 - 383
  • [40] Mirror writing ability in right- and left-handed adults: Ipsilateral control?
    Vaid, J
    Carr, J
    BRAIN AND COGNITION, 1999, 40 (01) : 264 - 268
12345