Selective isomerization of aryl substituted epoxides to aldehydes via iron Lewis acid catalysis

被引：23

作者：

Picione, J ^{[1
]}

Mahmood, SJ ^{[1
]}

Gill, A ^{[1
]}

Hilliard, M ^{[1
]}

Hossain, MM ^{[1
]}

机构：

[1] Univ Wisconsin, Dept Chem, Milwaukee, WI 53201 USA

来源：

TETRAHEDRON LETTERS | 1998年 / 39卷 / 18期

基金：

美国国家卫生研究院;

关键词：

D O I：

10.1016/S0040-4039(98)00371-2

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

The iron Lewis acid [(eta(5)-C5H5)Fe(CO)(2)(THF)]+BF4- (2) catalyzes the ring opening isomerization of aryl substituted epoxides (1) to aldehydes (3) in excellent yield. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：2681 / 2684

页数：4

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