CHEMOSELECTIVE AND REGIOSELECTIVE ISOMERIZATION OF EPOXIDES TO CARBONYL-COMPOUNDS VIA PALLADIUM CATALYSIS

被引：63
|
作者：
KULASEGARAM, S [1 ]
KULAWIEC, RJ [1 ]
机构：
[1] GEORGETOWN UNIV,DEPT CHEM,WASHINGTON,DC 20057
来源：
JOURNAL OF ORGANIC CHEMISTRY | 1994年 / 59卷 / 24期
关键词：
D O I：
10.1021/jo00103a005
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
Palladium(O)-tertiary phosphine complexes catalyze the chemo- and regioselective isomerization of epoxides to carbonyl compounds in good to excellent yields; alkyl-substituted epoxides afford methyl ketones, and aryl-substituted epoxides form aldehydes or ketones via cleavage of the benzylic C-O bond.
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页码：7195 / 7196
页数：2
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