Selective isomerization of aryl substituted epoxides to aldehydes via iron Lewis acid catalysis

被引：23
|
作者：
Picione, J [1 ]
Mahmood, SJ [1 ]
Gill, A [1 ]
Hilliard, M [1 ]
Hossain, MM [1 ]
机构：
[1] Univ Wisconsin, Dept Chem, Milwaukee, WI 53201 USA
来源：
TETRAHEDRON LETTERS | 1998年 / 39卷 / 18期
基金：
美国国家卫生研究院;
关键词：
D O I：
10.1016/S0040-4039(98)00371-2
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
The iron Lewis acid [(eta(5)-C5H5)Fe(CO)(2)(THF)]+BF4- (2) catalyzes the ring opening isomerization of aryl substituted epoxides (1) to aldehydes (3) in excellent yield. (C) 1998 Elsevier Science Ltd. All rights reserved.
引用
收藏
页码：2681 / 2684
页数：4
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