Disiloxanediolates and polyhedral metallasilsesquioxanes of the early transition metals and f-elements

被引：180
|
作者：
Lorenz, V
Fischer, A
Giessmann, S
Gilje, JW
Gun'ko, Y
Jacob, K
Edelmann, FT
机构：
[1] Univ Magdeburg, Inst Chem, D-39106 Magdeburg, Germany
[2] James Madison Univ, Dept Chem, Harrisonburg, VA 22807 USA
[3] Univ Dublin Trinity Coll, Dept Chem, Dublin 2, Ireland
[4] Univ Halle Wittenberg, Inst Anorgan Chem, Fachbereich Chem, D-06099 Halle, Germany
来源：
COORDINATION CHEMISTRY REVIEWS | 2000年 / 206卷
关键词：
disiloxanediolates; metallasilsesquioxanes; silsesquioxanes; lanthanides; actinides; early transition metals;
D O I：
10.1016/S0010-8545(00)00299-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two modern areas of metallasiloxane chemistry are reviewed. The first part deals with the preparation and structural characterization of the first f-element compounds derived from tetraphenylsisiloxanediol. In the second part recent developments in the chemistry of polyhedral metallasilsesquioxanes are surveyed, with special emphasis being placed on early transition metal and f-element derivatives. Also highlighted are applications of these species in catalysis research. (C) 2000 Elsevier Science S.A. AU rights reserved.
引用
收藏
页码：321 / 368
页数：48
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