Disiloxanediolates and polyhedral metallasilsesquioxanes of the early transition metals and f-elements

被引：180
|
作者：
Lorenz, V
Fischer, A
Giessmann, S
Gilje, JW
Gun'ko, Y
Jacob, K
Edelmann, FT
机构：
[1] Univ Magdeburg, Inst Chem, D-39106 Magdeburg, Germany
[2] James Madison Univ, Dept Chem, Harrisonburg, VA 22807 USA
[3] Univ Dublin Trinity Coll, Dept Chem, Dublin 2, Ireland
[4] Univ Halle Wittenberg, Inst Anorgan Chem, Fachbereich Chem, D-06099 Halle, Germany
来源：
COORDINATION CHEMISTRY REVIEWS | 2000年 / 206卷
关键词：
disiloxanediolates; metallasilsesquioxanes; silsesquioxanes; lanthanides; actinides; early transition metals;
D O I：
10.1016/S0010-8545(00)00299-X
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
Two modern areas of metallasiloxane chemistry are reviewed. The first part deals with the preparation and structural characterization of the first f-element compounds derived from tetraphenylsisiloxanediol. In the second part recent developments in the chemistry of polyhedral metallasilsesquioxanes are surveyed, with special emphasis being placed on early transition metal and f-element derivatives. Also highlighted are applications of these species in catalysis research. (C) 2000 Elsevier Science S.A. AU rights reserved.
引用
收藏
页码：321 / 368
页数：48
相关论文
共 50 条
  • [21] COMPLEXATION KINETICS OF F-ELEMENTS AND POLYDENTATE LIGANDS
    CHOPPIN, GR
    JOURNAL OF ALLOYS AND COMPOUNDS, 1995, 225 (1-2) : 242 - 245
  • [22] EXTRACTION OF F-ELEMENTS WITH SOFT DONOR ADDUCTS
    CHOPPIN, GR
    YAO, J
    WHARF, RM
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1994, 207 : 197 - IEC
  • [23] Spectroscopic studies of F-elements in silicates.
    Assefa, Z
    Haire, RG
    Stump, NA
    ABSTRACTS OF PAPERS OF THE AMERICAN CHEMICAL SOCIETY, 1999, 218 : U1078 - U1078
  • [24] Main groups and f-elements, NMR spectra
    Haser, M
    NACHRICHTEN AUS CHEMIE TECHNIK UND LABORATORIUM, 1997, 45 (02): : 185 - 187
  • [25] MOLECULAR-COMPOUNDS OF THE F-ELEMENTS - FOREWORD
    EPHRITIKHINE, M
    NEW JOURNAL OF CHEMISTRY, 1995, 19 (5-6) : 479 - 479
  • [26] EFFECT OF SOLVENT ON SORPTION OF BIVALENT F-ELEMENTS
    VELESHKO, IE
    MIKHEEV, NB
    KULYUKHIN, SA
    RADIOCHEMISTRY, 1993, 35 (06) : 687 - 689
  • [27] Novel phosphorylated calixarenes for the recognition of f-elements
    Karavan, Maria
    Arnaud-Neu, Francois
    Hubscher-Bruder, Veronique
    Smirnov, Igor
    Kalchenko, Vitaly
    JOURNAL OF INCLUSION PHENOMENA AND MACROCYCLIC CHEMISTRY, 2010, 66 (1-2) : 113 - 123
  • [28] SOLID COMPOUNDS OF F-ELEMENTS AND D-ELEMENTS AS GENERATORS OF FLUORINE
    OSTROPIKOV, VV
    RAKOV, EG
    IZVESTIYA VYSSHIKH UCHEBNYKH ZAVEDENII KHIMIYA I KHIMICHESKAYA TEKHNOLOGIYA, 1989, 32 (08): : 3 - 17
  • [29] Tripodal diglycolamides as highly efficient extractants for f-elements
    Janczewski, Dominik
    Reinhoudt, David N.
    Verboom, Willem
    Hill, Clement
    Allignol, Cecile
    Duchesne, Marie-Therese
    NEW JOURNAL OF CHEMISTRY, 2008, 32 (03) : 490 - 495
  • [30] Chemical inhomogeneity in materials with f-elements: observation and interpretation
    Vasilyeva, IG
    JOURNAL OF ALLOYS AND COMPOUNDS, 2001, 323 : 34 - 38
12345