Synthesis, structure, and reductive elimination reactions of the first (σ-aryl)palladium complex stabilized by IPr N-heterocyclic carbene

被引：72
|
作者：
Marshall, WJ [1 ]
Grushin, VV [1 ]
机构：
[1] EI DuPont De Nemours & Co Inc, Cent Res & Dev, Expt Stn, Wilmington, DE 19880 USA
来源：
ORGANOMETALLICS | 2003年 / 22卷 / 08期
关键词：
D O I：
10.1021/om030099t
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The first (s-aryl)palladium complex stabilized with one IPr N-heterocyclic carbene and one PPh3 ligand has been synthesized via a novel method, structurally characterized, and found to undergo remarkably facile C-C reductive elimination of the 2-phenylimida-zolium cation via phosphine predissociation.
引用
收藏
页码：1591 / 1593
页数：3
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