Synthesis and structure of C2-symmetric N-heterocyclic carbene complexes of palladium

被引:53
|
作者
Marshall, C [1 ]
Ward, MF [1 ]
Harrison, WTA [1 ]
机构
[1] Univ Aberdeen, Dept Chem, Aberdeen AB24 3UE, Scotland
关键词
C-2-symmetric; carbene; benzimidazol-2-ylidene palladium(II) complexes;
D O I
10.1016/j.tetlet.2004.05.085
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The first 9- and 11-membered cis and trans C-2-symmetric benzimidazol-2-ylidene palladium(11) complexes based on a trans-2,2-dimethyl-1,3-dioxalane backbone were synthesised and the configuration of the complexes was elucidated via NMR and X-ray crystallography. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码:5703 / 5706
页数:4
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