Progress of enantio-differentiating hydrogenation of prochiral ketones over asymmetrically modified nickel catalysts and a newly proposed enantio-differentiation model

被引：101

作者：

Osawa, T ^{[1
]}

Harada, T

Takayasu, O

机构：

[1] Toyama Univ, Fac Sci, Gofu Ku, Toyama 9308555, Japan

[2] Ryukoku Univ, Fac Sci & Technol, Otsu, Shiga 5202194, Japan

来源：

TOPICS IN CATALYSIS | 2000年 / 13卷 / 03期

关键词：

enantio-differentiating; hydrogenation; modified Ni; tartaric acid; methyl acetoacetate; alkanone;

D O I：

10.1023/A:1009042602411

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This article reviews the enantio-differentiating hydrogenation of various prochiral ketones over asymmetrically modified Ni catalysts. Development from the discovery to the state of the art of the modified Ni catalyst is surveyed. Understanding and interpretation of this catalyst is discussed and new enantio-differentiation models are proposed.

引用

页码：155 / 168

页数：14

共 50 条

[31] A substrate specific chiral modifier activation on enantio-differentiating hydrogenation over tartaric acid-modified Raney nickel
Nakagawa, S
Sugimura, T
Tai, A
CHEMISTRY LETTERS, 1998, (12) : 1257 - 1258
[32] ENANTIO-DIFFERENTIATING HYDROGENATION OF 2-ALKANONES OVER ASYMMETRICALLY MODIFIED NICKEL-CATALYST AND ITS APPLICATION TO THE PREPARATION OF OPTICALLY PURE 2-ALKANOLS
OSAWA, T
HARADA, T
TAI, A
JOURNAL OF CATALYSIS, 1990, 121 (01) : 7 - 17
[33] Repeated use of the in-situ modified nickel catalyst for the enantio-differentiating hydrogenation of 2-octanone
Osawa, T
Sawada, K
Harada, T
Takayasu, O
APPLIED CATALYSIS A-GENERAL, 2004, 264 (01) : 33 - 36
[34] Recent progress in tartaric acid‐modified Raney nickel system for enantio‐differentiating hydrogenation
Takashi Sugimura
Catalysis Surveys from Asia, 1999, 3 : 37 - 42
[35] Enantio-differentiating hydrogenation of methyl 2-furoylacetate and its analogs over tartaric acid-modified Raney nickel
Nakagawa, S
Haruna, N
Acosta, DE
Endo, T
Sugimura, T
Tai, A
CHEMISTRY LETTERS, 1999, (10) : 1055 - 1056
[36] Enantio-differentiating hydrogenation of methyl acetoacetate over tartaric acid-NaBr-modified supported nickel catalyst prepared from nickel acetylacetonate
Osawa, T
Mita, S
Iwai, A
Takayasu, O
Hashiba, H
Hashimoto, S
Harada, T
Matsuura, I
JOURNAL OF MOLECULAR CATALYSIS A-CHEMICAL, 2000, 157 (1-2) : 207 - 216
[37] Studies of the effects of the modification conditions on the hydrogenation rate for the enantio-differentiating hydrogenation of methyl acetoacetate over a tartaric acid-NaBr-modified nickel catalyst
Osawa, Tsutomu
Hagino, Yu
Harada, Tadao
Takayasu, Osamu
CATALYSIS LETTERS, 2006, 112 (1-2) : 57 - 61
[38] The development of asymmetrically modified nickel catalyst (MNi) of high enantio-differentiating ability (e.d.a.) based on the stereochemical approach
Tai, A
JOURNAL OF SYNTHETIC ORGANIC CHEMISTRY JAPAN, 2000, 58 (06) : 568 - 577
[39] Studies of the effects of the modification conditions on the hydrogenation rate for the enantio-differentiating hydrogenation of methyl acetoacetate over a tartaric acid–NaBr-modified nickel catalyst
Tsutomu Osawa
Yu Hagino
Tadao Harada
Osamu Takayasu
Catalysis Letters, 2006, 112 : 57 - 61
[40] Enantio-differentiating hydrogenation of methyl acetoacetate over tartaric acid-NaBr-modified Raney nickel catalyst under a low hydrogen pressure
Tsutomu Osawa
Mari Onogi
I-Yin Sandy Lee
Tadao Harada
Reaction Kinetics, Mechanisms and Catalysis, 2011, 103 : 443 - 449

← 1 2 3 4 5 →