Progress of enantio-differentiating hydrogenation of prochiral ketones over asymmetrically modified nickel catalysts and a newly proposed enantio-differentiation model

被引：101

作者：

Osawa, T ^{[1
]}

Harada, T

Takayasu, O

机构：

[1] Toyama Univ, Fac Sci, Gofu Ku, Toyama 9308555, Japan

[2] Ryukoku Univ, Fac Sci & Technol, Otsu, Shiga 5202194, Japan

来源：

TOPICS IN CATALYSIS | 2000年 / 13卷 / 03期

关键词：

enantio-differentiating; hydrogenation; modified Ni; tartaric acid; methyl acetoacetate; alkanone;

D O I：

10.1023/A:1009042602411

中图分类号：

O69 [应用化学];

学科分类号：

081704 ;

摘要：

This article reviews the enantio-differentiating hydrogenation of various prochiral ketones over asymmetrically modified Ni catalysts. Development from the discovery to the state of the art of the modified Ni catalyst is surveyed. Understanding and interpretation of this catalyst is discussed and new enantio-differentiation models are proposed.

引用

页码：155 / 168

页数：14

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