First total synthesis of (+)-Carainterol A

被引:23
|
作者
Ma, Kaiqing [1 ]
Zhang, Chunbo [2 ]
Liu, Mingming [1 ]
Chu, Yong [1 ]
Zhou, Lu [1 ]
Hu, Changqi [1 ]
Ye, Deyong [1 ]
机构
[1] Fudan Univ, Sch Pharm, Dept Med Chem, Shanghai 201203, Peoples R China
[2] Yanbian Univ, Minist Educ, Key Lab Nat Resources & Funct Mol Changbai Mt, Yanji 133000, Jilin, Peoples R China
基金
美国国家科学基金会;
关键词
CARBONYL-COMPOUNDS; ENANTIOSELECTIVE SYNTHESIS; GRIGNARD-REAGENTS; SESQUITERPENOIDS; EUDESMANE; ALCOHOLS; KETONES;
D O I
10.1016/j.tetlet.2010.02.001
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The first, stereospecific, and elegant synthesis of the natural product (+)-Carainterol A was developed by using the Robinson annulation reaction as a key step to build the eudesmane skeleton. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1870 / 1872
页数:3
相关论文
共 50 条
  • [41] The first total synthesis of (+)-mucosin
    Henderson, Alan R.
    Stec, Jozef
    Owen, David R.
    Whitby, Richard J.
    CHEMICAL COMMUNICATIONS, 2012, 48 (28) : 3409 - 3411
  • [42] The first total synthesis of isoliquiritin
    Wang, YP
    Li, LX
    Wang, QL
    Li, YL
    CHINESE CHEMICAL LETTERS, 2002, 13 (10) : 929 - 930
  • [43] First total synthesis of (±) Maackin
    Yang, Y
    Bie, PY
    Zhang, CL
    Pan, XF
    JOURNAL OF CHEMICAL RESEARCH, 2003, (05) : 266 - 267
  • [44] First total synthesis of Boehmenan
    Xia, Yamu
    Dai, Xiaoli
    Liu, Haixin
    Chai, Chen
    JOURNAL OF CHEMICAL SCIENCES, 2014, 126 (03) : 813 - 820
  • [45] The first total synthesis of (±)-sinaiticin
    She, XG
    Gu, WX
    Jing, XB
    Pan, XF
    CHEMICAL JOURNAL OF CHINESE UNIVERSITIES-CHINESE, 2000, 21 (09): : 1395 - 1398
  • [46] First total synthesis of kipukasin A
    Li, Chuang
    Ding, Haixin
    Ruan, Zhizhong
    Zhou, Yirong
    Xiao, Qiang
    BEILSTEIN JOURNAL OF ORGANIC CHEMISTRY, 2017, 13 : 855 - 862
  • [47] The first total synthesis of telephiose A
    Sato, Ken-ichi
    Sakai, Koudai
    Tsushima, Keiko
    Akai, Shoji
    TETRAHEDRON LETTERS, 2007, 48 (21) : 3745 - 3748
  • [48] First Total Synthesis of (±)-Powelline
    Anwar, Hany F.
    Hansen, Trond Vidar
    SYNLETT, 2008, (17) : 2681 - 2683
  • [49] The First Total Synthesis of Isoliquiritin
    Ya Ping WANG
    Chinese Chemical Letters, 2002, (10) : 929 - 930
  • [50] The first total synthesis of glycyrol
    Jin, Ying Lan
    Kim, Sanghee
    Kim, Yeong Shik
    Kim, Soon-Ai
    Kim, Hak Sung
    TETRAHEDRON LETTERS, 2008, 49 (48) : 6835 - 6837