First total synthesis of (+)-Carainterol A

被引:23
|
作者
Ma, Kaiqing [1 ]
Zhang, Chunbo [2 ]
Liu, Mingming [1 ]
Chu, Yong [1 ]
Zhou, Lu [1 ]
Hu, Changqi [1 ]
Ye, Deyong [1 ]
机构
[1] Fudan Univ, Sch Pharm, Dept Med Chem, Shanghai 201203, Peoples R China
[2] Yanbian Univ, Minist Educ, Key Lab Nat Resources & Funct Mol Changbai Mt, Yanji 133000, Jilin, Peoples R China
基金
美国国家科学基金会;
关键词
CARBONYL-COMPOUNDS; ENANTIOSELECTIVE SYNTHESIS; GRIGNARD-REAGENTS; SESQUITERPENOIDS; EUDESMANE; ALCOHOLS; KETONES;
D O I
10.1016/j.tetlet.2010.02.001
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
The first, stereospecific, and elegant synthesis of the natural product (+)-Carainterol A was developed by using the Robinson annulation reaction as a key step to build the eudesmane skeleton. (C) 2010 Elsevier Ltd. All rights reserved.
引用
收藏
页码:1870 / 1872
页数:3
相关论文
共 50 条
  • [31] FIRST TOTAL SYNTHESIS OF (-)-DEHYDROCARISSONE
    LIU, LJ
    XIONG, ZM
    NAN, FJ
    LI, TS
    LI, YL
    BULLETIN DES SOCIETES CHIMIQUES BELGES, 1995, 104 (02): : 73 - 76
  • [32] First total synthesis of paecilodepsipeptide A
    Yang, Ming Jun
    Wu, Jing
    Yang, Zhong Duo
    Zhang, Ying Mei
    CHINESE CHEMICAL LETTERS, 2009, 20 (05) : 527 - 530
  • [33] The first total synthesis of (±)-lagopodin A
    Srikrishna, A
    Lakshmi, BV
    Ravikumar, PC
    TETRAHEDRON LETTERS, 2006, 47 (08) : 1277 - 1281
  • [34] First total synthesis of paecilodepsipeptide A
    Ming Jun Yang~(a
    ChineseChemicalLetters, 2009, 20 (05) : 527 - 530
  • [35] First total synthesis of (±)-trolline
    Qiu Qin He
    ChineseChemicalLetters, 2007, (06) : 651 - 652
  • [36] The first total synthesis of (-)-tamandarin A
    Liang, B
    Portonovo, P
    Vera, MD
    Xiao, D
    Joullié, MM
    ORGANIC LETTERS, 1999, 1 (08) : 1319 - 1322
  • [37] The First Total Synthesis of Gravicycle
    Ueda, Katsuaki
    Sato, Itaru
    Hirama, Masahiro
    CHEMISTRY LETTERS, 2012, 41 (01) : 87 - 89
  • [38] First Total Synthesis of Rhodexin A
    Jung, Michael E.
    Yoo, Dongwon
    ORGANIC LETTERS, 2011, 13 (10) : 2698 - 2701
  • [39] THE FIRST TOTAL SYNTHESIS OF (-)-LIPSTATIN
    POMMIER, A
    PONS, JM
    KOCIENSKI, PJ
    JOURNAL OF ORGANIC CHEMISTRY, 1995, 60 (22): : 7334 - 7339
  • [40] The first total synthesis of discorhabdin A
    Tohma, H
    Harayama, Y
    Hashizume, M
    Iwata, M
    Kiyono, Y
    Egi, M
    Kita, Y
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 2003, 125 (37) : 11235 - 11240