New preparation of 1,2,4,5-tetraoxanes

被引：66

作者：

Terent'ev, AO

Kutkin, AV

Starikova, ZA

Antipin, MY

Ogibin, YN

Nikishina, GI

机构：

[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia

[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia

来源：

SYNTHESIS-STUTTGART | 2004年 / 14期

关键词：

tetraoxanes; heterocycles; peroxides; acetals; boron;

D O I：

10.1055/s-2004-831171

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A convenient procedure was developed for the synthesis of 1,2,4,5-tetraoxanes based on the reaction of gem-bishydroperoxycycloalkanes with ketals and acetals catalyzed by boron trifluoride etherate, which makes it possible to prepare the target products in yields from 13 to 93%.

引用

页码：2356 / 2366

页数：11

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