New preparation of 1,2,4,5-tetraoxanes

被引：66
|
作者：
Terent'ev, AO
Kutkin, AV
Starikova, ZA
Antipin, MY
Ogibin, YN
Nikishina, GI
机构：
[1] Russian Acad Sci, ND Zelinskii Organ Chem Inst, Moscow 119991, Russia
[2] Russian Acad Sci, AN Nesmeyanov Organoelement Cpds Inst, Moscow 119991, Russia
来源：
SYNTHESIS-STUTTGART | 2004年 / 14期
关键词：
tetraoxanes; heterocycles; peroxides; acetals; boron;
D O I：
10.1055/s-2004-831171
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
A convenient procedure was developed for the synthesis of 1,2,4,5-tetraoxanes based on the reaction of gem-bishydroperoxycycloalkanes with ketals and acetals catalyzed by boron trifluoride etherate, which makes it possible to prepare the target products in yields from 13 to 93%.
引用
收藏
页码：2356 / 2366
页数：11
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