(EtZn)4Zn2(PSitBu3)4 -: a homometallic phosphanediide of zinc with a novel Zn6P4 cage

被引：7
|
作者：
Westerhausen, M
Sapelza, G
Zabel, M
Pfitzner, A
机构：
[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany
[2] Univ Regensburg, Inst Inorgan Chem, D-93040 Regensburg, Germany
来源：
ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2004年 / 59卷 / 11-12期
关键词：
cage compounds; geminal dianions; metalation; phosphanediides; zinc;
D O I：
10.1515/znb-2004-11-1227
中图分类号：
O61 [无机化学];
学科分类号：
070301 ; 081704 ;
摘要：
The metalation of tri(tert-butyl)silylphosphane with diethylzinc yields quantitatively the title compound tetraethyltetrakis(tri(tert-butyl)silylphosphanediido)hexazinc (1) with a novel Zn6P4 cage with two Zn2P2 rings interconnected by two zinc atoms.
引用
收藏
页码：1548 / 1550
页数：3
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