(EtZn)4Zn2(PSitBu3)4 -: a homometallic phosphanediide of zinc with a novel Zn6P4 cage

被引：7

作者：

Westerhausen, M

Sapelza, G

Zabel, M

Pfitzner, A

机构：

[1] Univ Munich, Dept Chem & Biochem, D-81377 Munich, Germany

[2] Univ Regensburg, Inst Inorgan Chem, D-93040 Regensburg, Germany

来源：

ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES | 2004年 / 59卷 / 11-12期

关键词：

cage compounds; geminal dianions; metalation; phosphanediides; zinc;

D O I：

10.1515/znb-2004-11-1227

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

The metalation of tri(tert-butyl)silylphosphane with diethylzinc yields quantitatively the title compound tetraethyltetrakis(tri(tert-butyl)silylphosphanediido)hexazinc (1) with a novel Zn6P4 cage with two Zn2P2 rings interconnected by two zinc atoms.

引用

页码：1548 / 1550

页数：3

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