Aqueous phase reforming of biocrude derived from lignocellulose hydrothermal liquefaction: Conditions optimization and mechanism study

Hydrothermal liquefaction (HTL) of biomass into biocrude is attractive but the biocrude themselves are poor fuels, which need to be upgraded for further utilization. Compared with the traditional catalytic upgradation process, a non-catalytic method for biocrude upgrading in the aqueous waste (HTL-AW) derived from HTL of cornstalk was proposed. Optimal reaction conditions of upgradation process were obtained at 356 degrees C (temperature), 37 min (reaction time) and 19 mL/g (HTL-AW/biocrude) based on the response surface methodology. The biocrude was effectively upgraded in the HTL-AW and a high hydrogen to carbon effective (H/C-eff) ratio of 1.07 with a higher heating value of 36.94 MJ/kg was observed. The energy recovery of similar to 80% from biocrude to upgraded biocrude was feasible. GC-MS analysis showed that the contents of phenols and ketones were decreased from 65.61% to 48.38% and 22.39%-16.78%, respectively, while the contents of nitrogen-containing compounds n-hexadecanoic acid were increased from 2.25% to 10.15% and 9.56%-22.23%, respectively. The high H/C-eff was attributed to the promoted deoxygenation by alkali and alkaline earth metals as well as Hthorn enriched in the HTL-AW. This study demonstrates the feasibility of improving the H/C-eff of biocrude in the HTL-AW under a relatively mild reaction condition. (C) 2021 Elsevier Ltd. All rights reserved.