Electroluminescence and aggregation in fluorene-thiophene-S,S-dioxide: Oligomers and polymers

被引:4
|
作者
Destri, S
Pasini, M
Porzio, W
Giovanella, U
Gigli, G
Pisignano, D
机构
[1] CNR, Ist Studio Macromol, I-20133 Milan, Italy
[2] INFM, Natl Nanotechnol Lab, I-73100 Lecce, Italy
关键词
photoluminescence; oligomers; fluorene; S; S-dioxide group;
D O I
10.1016/S0379-6779(02)00665-3
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
We report on the preparation of both 2,5-di(9,9-dimethyl)fluorenyl-3,4-dihexyl-thiophene-S,S-dioxide and the related polymer with longer alkyl substitutions at 9 position. The optical, structural, and morphological characterizations of crystals and films showing noticeable EL properties are presented. Light emitting diodes (LEDs) show for the first time a good external efficiency (10(-1)) for a polymer containing S,S-dioxide groups.
引用
收藏
页码:409 / 410
页数:2
相关论文
共 50 条
  • [41] Thermal bleaching reactions of photochromic diarylethenes with thiophene-S,S-dioxide for a light-starting irreversible thermosensor
    Shoji, Hiroaki
    Kobatake, Seiya
    CHEMICAL COMMUNICATIONS, 2013, 49 (23) : 2362 - 2364
  • [42] IN PURSUIT OF CYCLOPROPANETHIONE - CYCLOPROPANETHIONE S-OXIDE AND S,S-DIOXIDE
    BLOCK, E
    SCHWAN, A
    DIXON, DA
    JOURNAL OF THE AMERICAN CHEMICAL SOCIETY, 1992, 114 (09) : 3492 - 3499
  • [43] C-C bond cleavage in the oxidation of 2-hydroxyoxathiane S,S-dioxide and 2,2'-sulfanediyldiethanol S,S-dioxide
    Hammad, N
    Sutherland, AG
    JOURNAL OF CHEMICAL RESEARCH-S, 1996, (03): : 158 - 159
  • [44] Synthesis and physical properties of [4]cyclo-3,7-dibenzo[b,d]thiophene and its S,S-dioxide
    Kayahara, Eiichi
    Zhai, Xue
    Yamago, Shigeru
    CANADIAN JOURNAL OF CHEMISTRY, 2017, 95 (04) : 351 - 356
  • [45] STEROCHEMISTRY OF 3,4-DIBROMOTHIOCHROMANE S,S-DIOXIDE
    PAGANI, G
    MAIORANA, S
    BRADAMAN.S
    CHIMICA & L INDUSTRIA, 1971, 53 (04): : 363 - &
  • [46] Dithienothiophene and dithienothiophene-S,S-dioxide copolymers for photovoltaics
    Catellani, M
    Boselli, B
    Luzzati, S
    Tripodi, C
    THIN SOLID FILMS, 2002, 403 : 66 - 70
  • [47] Molybdenum and tungsten complexes of sulfene (thioformaldehyde S,S-dioxide)
    Schenk, WA
    Nielsen, K
    Burzlaff, NI
    Hagel, M
    INORGANIC CHEMISTRY, 2002, 41 (05) : 1079 - 1085
  • [48] CHARGE-DENSITY STUDY OF THIOUREA S,S-DIOXIDE
    WANG, Y
    CHANG, NL
    PAI, CT
    INORGANIC CHEMISTRY, 1990, 29 (17) : 3256 - 3259
  • [49] MECHANISTIC INVESTIGATIONS OF THE CYCLOADDITION REACTIONS OF THIOXANTHENYLIDENE S,S-DIOXIDE
    ABDELWAHAB, AA
    DOSS, SH
    DURR, H
    TURRO, NJ
    GOULD, IR
    JOURNAL OF ORGANIC CHEMISTRY, 1987, 52 (03): : 429 - 434
  • [50] Bluish-Green Light-Emitting Polymers Based on Polycarbazole Containing Benzo[b]naphtho[1,2-d]thiophene-S,S-dioxide Unit
    Zhang, Yuhao
    Xu, Jin
    Yang, Wei
    KOREAN JOURNAL OF CHEMICAL ENGINEERING, 2025, 42 (02) : 445 - 454