Enzymatic reactions in supercritical CO2:: carboxylation, asymmetric reduction and esterification

被引：52
|
作者：
Matsuda, T [1 ]
Watanabe, K
Harada, T
Nakamura, K
机构：
[1] Ryukoku Univ, Dept Chem Mat, Shiga, Japan
[2] Kyoto Univ, Inst Chem Res, Kyoto 606, Japan
来源：
CATALYSIS TODAY | 2004年 / 96卷 / 03期
关键词：
supercritical CO2; enzyme; decarboxylase; alcohol dehydrogenase; lipase; enantioselectivity; carboxylation; reduction; esterification; chiral ompounds; trifluoromethyl alcohol;
D O I：
10.1016/j.cattod.2004.06.111
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Catalytic reactions in supercritical CO2 have been receiving increased attention during the last decade. This report reviews enzymatic reactions in supercritical CO2 such as carboxylation of pyrrole by a decarboxylase, asymmetric reduction of ketones by an alcohol dehydrogenase and enantioselective esterification of a trifluoromethyl alcohol by a lipase. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：103 / 111
页数：9
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