Enzymatic reactions in supercritical CO2:: carboxylation, asymmetric reduction and esterification

被引：52
|
作者：
Matsuda, T [1 ]
Watanabe, K
Harada, T
Nakamura, K
机构：
[1] Ryukoku Univ, Dept Chem Mat, Shiga, Japan
[2] Kyoto Univ, Inst Chem Res, Kyoto 606, Japan
来源：
CATALYSIS TODAY | 2004年 / 96卷 / 03期
关键词：
supercritical CO2; enzyme; decarboxylase; alcohol dehydrogenase; lipase; enantioselectivity; carboxylation; reduction; esterification; chiral ompounds; trifluoromethyl alcohol;
D O I：
10.1016/j.cattod.2004.06.111
中图分类号：
O69 [应用化学];
学科分类号：
081704 ;
摘要：
Catalytic reactions in supercritical CO2 have been receiving increased attention during the last decade. This report reviews enzymatic reactions in supercritical CO2 such as carboxylation of pyrrole by a decarboxylase, asymmetric reduction of ketones by an alcohol dehydrogenase and enantioselective esterification of a trifluoromethyl alcohol by a lipase. (C) 2004 Elsevier B.V. All rights reserved.
引用
收藏
页码：103 / 111
页数：9
相关论文
共 50 条
  • [21] POLAR SUBSTRATES FOR ENZYMATIC-REACTIONS IN SUPERCRITICAL CO2 - HOW TO OVERCOME THE SOLUBILITY LIMITATION
    CASTILLO, E
    MARTY, A
    COMBES, D
    CONDORET, JS
    BIOTECHNOLOGY LETTERS, 1994, 16 (02) : 169 - 174
  • [22] Production of isoamyl acetate by enzymatic reactions in batch and packed bed reactors with supercritical CO2
    dos Santos, Philipe
    Meireles, M. Angela A.
    Martinez, Julian
    JOURNAL OF SUPERCRITICAL FLUIDS, 2017, 127 : 71 - 80
  • [23] Continuous catalytic asymmetric hydrogenation in supercritical CO2
    Stephenson, P
    Licence, P
    Ross, SK
    Poliakoff, M
    GREEN CHEMISTRY, 2004, 6 (10) : 521 - 523
  • [24] Enhancement of enantioselectivity by altering alcohol concentration for esterification in supercritical CO2
    Wu, JY
    Liang, MT
    JOURNAL OF CHEMICAL ENGINEERING OF JAPAN, 1999, 32 (03) : 338 - 340
  • [25] PRESSURE EFFECT ON THE ESTERIFICATION OF PHTHALIC-ANHYDRIDE IN SUPERCRITICAL CO2
    ELLINGTON, JB
    BRENNECKE, JF
    JOURNAL OF THE CHEMICAL SOCIETY-CHEMICAL COMMUNICATIONS, 1993, (13) : 1094 - 1095
  • [26] Recent Advances in Copper-Catalyzed Carboxylation Reactions with CO2
    Song, Yufei
    Zhang, Yu
    Chen, Zhengkai
    Wu, Xiao-Feng
    ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2022, 11 (07)
  • [27] Carboxylation reactions for integrating CO2 capture with the production of renewable monomers
    Faba, Laura
    Rapado, Paula
    Ordonez, Salvador
    GREENHOUSE GASES-SCIENCE AND TECHNOLOGY, 2023, 13 (02) : 227 - 244
  • [28] Enzymatic ring opening polymerization of ε-caprolactone in supercritical CO2
    Nakaoki, T
    Kitoh, M
    Gross, RA
    POLYMER BIOCATALYSIS AND BIOMATERIALS, 2005, 900 : 393 - 404
  • [29] Reinforcing carbon fixation: CO2 reduction replacing and supporting carboxylation
    Cotton, Charles A. R.
    Edlich-Muth, Christian
    Bar-Even, Arren
    CURRENT OPINION IN BIOTECHNOLOGY, 2018, 49 : 49 - 56
  • [30] Electrochemical reduction of CO2 in a mixed supercritical fluid
    Abbott, AP
    Eardley, CA
    JOURNAL OF PHYSICAL CHEMISTRY B, 2000, 104 (04): : 775 - 779
12345