Poly[[bis(triphenylphosphine)mercury(II)]-μ-thiocyanato-cadmium(II)-tri-μ-thiocyanato]

被引:8
|
作者
Wang, XQ [1 ]
Yu, WT [1 ]
Xu, D [1 ]
Sun, HQ [1 ]
机构
[1] Shandong Univ, Inst Crystal Mat, State Key Lab Crystal Mat, Jinan 250100, Peoples R China
关键词
D O I
10.1107/S160053680500468X
中图分类号
O7 [晶体学];
学科分类号
0702 ; 070205 ; 0703 ; 080501 ;
摘要
The title complex, [CdHg(NCS)(4)(C18H15P)(2)](n), contains slightly distorted trigonal bipyramidal CdN4S and tetrahedral HgP2S2. The Cd-II atom is coordinated by the N atoms of four thiocyanate ions and the S atom of one thiocyanate ion. The Hg-II atom is coordinated by two triphenylphosphine P atoms and two thiocyanate S atoms. The two metal atoms, viz. Cd-II and Hg-II, are connected by an -S=C=N- bridge, forming an infinite three-dimensional network.
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页码:M548 / M550
页数:3
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