(Thiocyanato-kS)tris(thiourea-kS)-mercury(II) chloride

被引：6
|
作者：
Syed, A. Shihabuddeen [1 ]
Rajarajan, K. [2 ]
NizamMohideen, M. [3 ]
机构：
[1] Bharathiar Univ, Res & Dev Ctr, Coimbatore 641046, Tamil Nadu, India
[2] Rajeswari Vedachalam Govt Arts Coll, Dept Phys, Chengalpet 603001, India
[3] New Coll Autonomous, Dept Phys, Chennai 600014, Tamil Nadu, India
来源：
ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷
关键词：
single-crystal X-ray study; T = 293 K; mean sigma(N-C) = 0.007 A(degrees); R factor = 0.036; wR factor = 0.082; data-to-parameter ratio = 33.1;
D O I：
10.1107/S1600536813011847
中图分类号：
O7 [晶体学];
学科分类号：
0702 ; 070205 ; 0703 ; 080501 ;
摘要：
In the title salt, [Hg(NCS)(CH4N2S)(3)] Cl, the Hg (2+) ion is coordinated in a severely distorted tetrahedral manner by three thiourea groups and one thiocyanate anion through their S atoms. The S-Hg-S angles vary widely from 87.39 (5) to 128.02 (4)(degrees). Weak intramolecular N-H...S hydrogen bonds are observed, which form S( 6) ring motifs. In the crystal, the ions are linked by N-H...N and weak N-H...Cl interactions, generating a three-dimensional network.
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收藏
页码：I33 / +
页数：8
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