(Thiocyanato-kS)tris(thiourea-kS)-mercury(II) chloride

被引：6

作者：

Syed, A. Shihabuddeen ^{[1
]}

Rajarajan, K. ^{[2
]}

NizamMohideen, M. ^{[3
]}

机构：

[1] Bharathiar Univ, Res & Dev Ctr, Coimbatore 641046, Tamil Nadu, India

[2] Rajeswari Vedachalam Govt Arts Coll, Dept Phys, Chengalpet 603001, India

[3] New Coll Autonomous, Dept Phys, Chennai 600014, Tamil Nadu, India

来源：

ACTA CRYSTALLOGRAPHICA SECTION E-CRYSTALLOGRAPHIC COMMUNICATIONS | 2013年 / 69卷

关键词：

single-crystal X-ray study; T = 293 K; mean sigma(N-C) = 0.007 A(degrees); R factor = 0.036; wR factor = 0.082; data-to-parameter ratio = 33.1;

D O I：

10.1107/S1600536813011847

中图分类号：

O7 [晶体学];

学科分类号：

0702 ; 070205 ; 0703 ; 080501 ;

摘要：

In the title salt, [Hg(NCS)(CH4N2S)(3)] Cl, the Hg (2+) ion is coordinated in a severely distorted tetrahedral manner by three thiourea groups and one thiocyanate anion through their S atoms. The S-Hg-S angles vary widely from 87.39 (5) to 128.02 (4)(degrees). Weak intramolecular N-H...S hydrogen bonds are observed, which form S( 6) ring motifs. In the crystal, the ions are linked by N-H...N and weak N-H...Cl interactions, generating a three-dimensional network.

引用

页码：I33 / +

页数：8

共 22 条

[21] INFLUENCE OF BROMIDE, CHLORIDE AND THIOUREA ADDITIONS ON THE REDUCTION OF PB(II) FROM MOLTEN CA(NO3)2-4H2O AT THE MERCURY-ELECTRODE
NARAYAN, R
VALSARAJ, KT
ELECTROCHIMICA ACTA, 1982, 27 (01) : 153 - 158
[22] Synthesis, X-ray structure and 199Hg, 77Se CP MAS NMR studies on the first tris(imidazolidine-2-selone) mercury complex:: {Chloro-tris[N-methyl-2(3H)-imidazolidine-2-selone] mercury(II)} chloride
Al-Amri, AHD
Fettouhi, M
Wazeer, MIM
Isab, AA
INORGANIC CHEMISTRY COMMUNICATIONS, 2005, 8 (12) : 1109 - 1112

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