Stereoselective intramolecular oxazine formation by a π-allylpalladium complex catalyzed by Pd0

被引：13

作者：

Joo, Jae-Eun ^{[1
]}

Lee, Kee-Young ^{[1
]}

Pham, Van-Thoai ^{[1
]}

Ham, Won-Hun ^{[1
]}

机构：

[1] Sungkyunkwan Univ, Coll Pharm, Suwon 440746, South Korea

来源：

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 2007卷 / 10期

关键词：

stereoselective synthesis; chiral oxazine; catalysis; amino alcohol; palladium; synthetic methods;

D O I：

10.1002/ejoc.200600927

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

An efficient procedure for synthesizing oxazines was developed by the palladium (0) -catalyzed intramolecular cyclization of a benzamide through a pi-allylpalladium(II) complex. Unlike other palladium-catalyzed reactions, the temperature was found to be a key factor in determining the stereochemistry of the oxazine. ((c) Wiley-VCH Verlag GmbH & Co.

引用

页码：1586 / 1593

页数：8

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