Stereoselective intramolecular oxazine formation by a π-allylpalladium complex catalyzed by Pd0

被引：13
|
作者：
Joo, Jae-Eun [1 ]
Lee, Kee-Young [1 ]
Pham, Van-Thoai [1 ]
Ham, Won-Hun [1 ]
机构：
[1] Sungkyunkwan Univ, Coll Pharm, Suwon 440746, South Korea
来源：
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY | 2007年 / 2007卷 / 10期
关键词：
stereoselective synthesis; chiral oxazine; catalysis; amino alcohol; palladium; synthetic methods;
D O I：
10.1002/ejoc.200600927
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
An efficient procedure for synthesizing oxazines was developed by the palladium (0) -catalyzed intramolecular cyclization of a benzamide through a pi-allylpalladium(II) complex. Unlike other palladium-catalyzed reactions, the temperature was found to be a key factor in determining the stereochemistry of the oxazine. ((c) Wiley-VCH Verlag GmbH & Co.
引用
收藏
页码：1586 / 1593
页数：8
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