Total synthesis of microcarpalide

被引：46

作者：

Gurjar, MK ^{[1
]}

Nagaprasad, R ^{[1
]}

Ramana, CV ^{[1
]}

机构：

[1] Natl Chem Lab, Pune 411008, Maharashtra, India

来源：

TETRAHEDRON LETTERS | 2003年 / 44卷 / 14期

关键词：

D O I：

10.1016/S0040-4039(03)00441-6

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

A total synthesis of the natural product microcarpalide is described. Ring-closing metathesis of a dienic ester was used as the key step. Mannose was used as the chiral pool material for the construction of the olefinic-acid and a Sharpless asymmetric dihydroxylation reaction provided the chiral precursor for the synthesis of the olefinic-alcohol. (C) 2003 Elsevier Science Ltd. All rights reserved.

引用

页码：2873 / 2875

页数：3

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