Alkyl Esterification of Vinylarenes Enabled by Visible-Light-Induced Decarboxylation

被引：40

作者：

Ge, Liang ^{[1
]}

Li, Yajun ^{[1
]}

Jian, Wujun ^{[1
]}

Bao, Hongli ^{[1
]}

机构：

[1] Univ Chinese Acad Sci, Fujian Inst Res Struct Matter, Key Lab Coal Ethylene Glycol & Its Related Techno, State Key Lab Struct Chem, 155 Yangqiao Rd West, Fuzhou 350002, Fujian, Peoples R China

来源：

CHEMISTRY-A EUROPEAN JOURNAL | 2017年 / 23卷 / 49期

关键词：

alkyl esterification; carboxylic acids; photocatalysis; vinylarenes; visible light; REDOX-ACTIVE ESTERS; CATALYZED INTERMOLECULAR TRIFLUOROMETHYLARYLATION; HYPERVALENT IODINE REAGENTS; PHOTOREDOX CATALYSIS; MERGING PHOTOREDOX; DIACYL PEROXIDES; CARBOXYLIC-ACIDS; NICKEL CATALYSIS; ORGANIC-SYNTHESIS; ACYL PEROXIDES;

D O I：

10.1002/chem.201702385

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A decarboxylative alkyl esterification of vinylarenes induced by visible light is described. A variety of alkyl diacyl peroxides synthesized from readily available aliphatic carboxylic acids are used as not only the oxygenation but also alkylation source. This simple and easy to handle reaction has a wide substrate scope, excellent yields, and works under mild reaction conditions. Carbon dioxide is the sole byproduct. An oxidative quenching process is proposed as the mechanism.

引用

页码：11767 / 11770

页数：4

共 50 条

[41] Visible-light-induced alkyl-arylation of olefins via a halogen-atom transfer process
Ren, Juan
Xia, Xiao-Feng
ORGANIC & BIOMOLECULAR CHEMISTRY, 2024, 22 (31) : 6370 - 6375
[42] Visible-Light-Induced Multicomponent Synthesis of Tetrasubstituted Imidazoles
Borkotoky, Lodsna
Bora, Kaushik
Maurya, Ram Awatar
ASIAN JOURNAL OF ORGANIC CHEMISTRY, 2023, 12 (05)
[43] Illuminating Biology with Visible-Light-induced Biocompatible Reactions
Chen, Yiyun
CHEMPHOTOCHEM, 2020, 4 (05) : 319 - 320
[44] Visible-Light-Induced Sulfoxidation of Alkanes in the Presence of Titania
Parrino, Francesco
Ramakrishnan, Ayyappan
Damm, Cornelia
Kisch, Horst
CHEMPLUSCHEM, 2012, 77 (08): : 713 - 720
[45] Visible-Light-Induced Photoredox Catalysis with a TetraceriumContaining Silicotungstate**
Suzuki, Kosuke
Tang, Fei
Kikukawa, Yuji
Yamaguchi, Kazuya
Mizuno, Noritaka
ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2014, 53 (21) : 5356 - 5360
[46] Visible-light-induced alkylation of 2-iminochromene
Singh, Shashank
Singh, Ravi P.
ORGANIC & BIOMOLECULAR CHEMISTRY, 2022, 20 (40) : 7891 - 7895
[47] Visible-light-induced selective defluoroalkylations of polyfluoroarenes with alcohols
Xu, Wengang
Shao, Qi
Xia, Congjian
Zhang, Qiao
Xu, Yadi
Liu, Yingguo
Wu, Mingbo
CHEMICAL SCIENCE, 2023, 14 (04) : 916 - 922
[48] Rhenium Complexes with Visible-Light-Induced Anticancer Activity
Kastl, Anja
Dieckmann, Sandra
Waehler, Kathrin
Voelker, Timo
Kastl, Lena
Merkel, Anna Lena
Vultur, Adina
Shannan, Batool
Harms, Klaus
Ocker, Matthias
Parak, Wolfgang J.
Herlyn, Meenhard
Meggers, Eric
CHEMMEDCHEM, 2013, 8 (06) : 924 - 927
[49] Visible-Light-Induced N-Acylation of Sulfoximines
Qiu, Pan
Duan, Xuelun
Li, Ming
Zheng, Yubin
Song, Wangze
ORGANIC LETTERS, 2022, 24 (14) : 2733 - 2737
[50] Visible-light-induced regioselective synthesis of polyheteroaromatic compounds
Chatterjee, Tanmay
Choi, Myung Gil
Kim, Jun
Chang, Suk-Kyu
Cho, Eun Jin
CHEMICAL COMMUNICATIONS, 2016, 52 (22) : 4203 - 4206

← 1 2 3 4 5 →