Visible-light-induced regioselective synthesis of polyheteroaromatic compounds

被引:32
|
作者
Chatterjee, Tanmay [1 ]
Choi, Myung Gil [1 ]
Kim, Jun [1 ]
Chang, Suk-Kyu [1 ]
Cho, Eun Jin [1 ]
机构
[1] Chung Ang Univ, Dept Chem, 84 Heukseok Ro, Seoul 156756, South Korea
基金
新加坡国家研究基金会;
关键词
C-H ACTIVATION; PHOTOREDOX CATALYSIS; DIAZONIUM SALTS; PROBES; ALKYNES; DESIGN; TRIFLUOROMETHYLATION; DERIVATIVES; CONVERSION;
D O I
10.1039/c6cc00562d
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
A method for visible-light-induced synthesis of polyheteroaromatics from 2-heteroaryl-substituted anilines and heteroarylalkynes was developed. The process, which uses fac-Ir(ppy)(3) as the photocatalyst and (BuONO)-Bu-t as the diazotization reagent, is highly regioselective.
引用
收藏
页码:4203 / 4206
页数:4
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