Synthesis and electrochemical properties of poly(3,4-dihydroxystyrene) and its composites with conducting polymers

被引:7
|
作者
Lukyanov, D. A. [1 ]
Apraksin, R. V. [1 ]
Yankin, A. N. [1 ]
Vlasov, P. S. [1 ]
Levin, O. V. [1 ]
Tolstopjatova, E. G. [1 ]
Kondratiev, V. V. [1 ]
机构
[1] St Petersburg State Univ, St Petersburg 199034, Russia
关键词
Composite materials; Conducting polymers; Poly-3,4-ethylenedioxythiophene; Poly(3,4-dihydroxystyrene); Cyclic voltammetry; Electrochemical capacitors; REDOX; QUINONES;
D O I
10.1016/j.synthmet.2019.116151
中图分类号
T [工业技术];
学科分类号
08 ;
摘要
The present study reports electrochemical performance of electrode materials based on poly(3,4-dihydroxystyrene) (PDHS) and its composites with conducting polymer poly(3,4-ethylenedioxythiophene) (PEDOT), deposited on glassy carbon electrodes, in diluted sulfuric acid. Poly(3,4-dihydroxystyrene), bearing redox active hydroquinone groups, was employed to the first time as an electrode material in combination with carbon, binder and conducting polymer. It was found that this quinone-based composite exhibits moderate electrochemical characteristics with specific capacity of about 50-54 mA h g(-1). The comparison of rate constants obtained for GC/PDHS and GC/PEDOT/PDHS electrodes confirms the catalytic effect of conducting polymer PEDOT on the redox transformation of PDHS.
引用
收藏
页数:5
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