Chemical synthesis, characterization, and electrochemical studies of poly(3,4-ethylenedioxythiophene)/poly(styrene-4-sulfonate) composites

被引：145
|
作者：
Lefebvre, M [1 ]
Qi, ZG [1 ]
Rana, D [1 ]
Pickup, PG [1 ]
机构：
[1] Mem Univ Newfoundland, Dept Chem, St Johns, NF A1B 3X7, Canada
来源：
CHEMISTRY OF MATERIALS | 1999年 / 11卷 / 02期
关键词：
D O I：
10.1021/cm9804618
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
Poly(3,4-ethylenedioxythiophene)/poly(styrene-4-sulfonate) (PEDOT/PSS) composites have been prepared from aqueous and aqueous acetonitrile solutions of EDOT and NaPSS by oxidation using Fe(III) salts. Powders with PEDOT to PSS ratios ranging from 0.3 to 4.2 and electronic conductivities as high as 10 S cm(-1) have been obtained in good yields. The PEDOT/PSS blends are cation exchangers and exhibit facile electrochemistry in both aqueous and acetonitrile media. Impedance measurements have shown that 30 mu m thick PEDOT/PSS layers have proton conductivities as high as 0.03 S cm(-1).
引用
收藏
页码：262 / 268
页数：7
相关论文
共 50 条
  • [1] Ion transport in poly(3,4-ethylenedioxythiophene)-poly(styrene-4-sulfonate) composites
    Li, GC
    Pickup, PG
    [J]. PHYSICAL CHEMISTRY CHEMICAL PHYSICS, 2000, 2 (06) : 1255 - 1260
  • [2] Application of commercial poly(3,4-ethylenedioxythiophene):poly(styrene sulfonate) for electrochemical sensing of dopamine
    Yao, Yuanyuan
    Wen, Yangping
    Xu, Jingkun
    Zhang, Long
    Duan, Xuemin
    [J]. JOURNAL OF THE SERBIAN CHEMICAL SOCIETY, 2013, 78 (09) : 1397 - 1411
  • [3] Morphology of electrodeposited poly(3,4-ethylenedioxythiophene)/poly(4-styrene sulfonate) films
    Han, Dongxue
    Yang, Guifu
    Song, Jixia
    Niu, Li
    Ivaska, Ari
    [J]. JOURNAL OF ELECTROANALYTICAL CHEMISTRY, 2007, 602 (01) : 24 - 28
  • [4] Electromechanical Properties of Poly(3,4-ethylenedioxythiophene)/Poly(4-styrene sulfonate) Films
    Okuzaki, Hidenori
    Suzuki, Hiroki
    Ito, Takamichi
    [J]. JOURNAL OF PHYSICAL CHEMISTRY B, 2009, 113 (33): : 11378 - 11383
  • [5] Poly (3,4-ethylenedioxythiophene):poly (styrene sulfonate)/tin disulfide composites with enhanced thermoelectric properties
    Kalabak, Fevzi
    Ugraskan, Volkan
    [J]. FULLERENES NANOTUBES AND CARBON NANOSTRUCTURES, 2024,
  • [6] Characterization of poly(3,4-ethylenedioxythiophene)/poly(styrene sulfonate) (PEDOT:PSS) adsorption on cellulosic materials
    Elson Montibon
    Lars Järnström
    Magnus Lestelius
    [J]. Cellulose, 2009, 16 : 807 - 815
  • [7] Characterization of poly(3,4-ethylenedioxythiophene)/poly(styrene sulfonate) (PEDOT:PSS) adsorption on cellulosic materials
    Montibon, Elson
    Jarnstrom, Lars
    Lestelius, Magnus
    [J]. CELLULOSE, 2009, 16 (05) : 807 - 815
  • [8] Chemical synthesis of poly(3,4-ethylenedioxythiophene)
    Corradi, R
    Armes, SP
    [J]. SYNTHETIC METALS, 1997, 84 (1-3) : 453 - 454
  • [9] Electrochromic window based on conducting poly (3,4-ethylenedioxythiophene)poly(styrene sulfonate)
    Heuer, HW
    Wehrmann, R
    Kirchmeyer, S
    [J]. ADVANCED FUNCTIONAL MATERIALS, 2002, 12 (02) : 89 - 94
  • [10] Poly(3,4-Ethylenedioxythiophene):Poly(Styrene Sulfonate)/Boron Carbide Hybrid Composites with Improved Thermoelectric Performance
    Volkan Ugraskan
    Esra Tari
    Ozlem Yazici
    [J]. Journal of Electronic Materials, 2021, 50 : 5618 - 5624
12345