Fabrication of tubular NiO/YSZ anode-support of solid oxide fuel cell by gelcasting

被引:47
|
作者
Dong, Dehua [1 ]
Gao, Jianfeng [1 ]
Liu, Xingqin [1 ]
Meng, Guangyao [1 ]
机构
[1] Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Peoples R China
基金
中国国家自然科学基金;
关键词
gelcasting; solid oxide fuel cells; tubular anode-support; microstructure;
D O I
10.1016/j.jpowsour.2006.10.098
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A gelcasting process has been developed to fabricate tubular NiO/YSZ anode-support for solid oxide fuel cells (SOFCs) successfully. The theological behaviors of the ceramic particle suspensions for gelcasting were investigated as a function of the process parameters, such as the amount of pore former, pH value, dispersant concentration, monomer concentration, ball-mill time and solid loading. The sintering shrinkage, microstructure, bending strength and electrical conductivity of the sintered specimens were examined. The tubular Ni/YSZ anode-support obtained under the optimized preparation conditions exhibited a porosity of 39.6%, mean pore size of below 0.9 mu m, 482 s cm(-1) in electrical conductivity at 700 degrees C, and the bending strength of 112.8 MPa, which can well meet the requirements for SOFCs. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:217 / 223
页数:7
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