Fabrication of tubular NiO/YSZ anode-support of solid oxide fuel cell by gelcasting

被引:47
|
作者
Dong, Dehua [1 ]
Gao, Jianfeng [1 ]
Liu, Xingqin [1 ]
Meng, Guangyao [1 ]
机构
[1] Univ Sci & Technol China, Dept Mat Sci & Engn, Hefei 230026, Peoples R China
基金
中国国家自然科学基金;
关键词
gelcasting; solid oxide fuel cells; tubular anode-support; microstructure;
D O I
10.1016/j.jpowsour.2006.10.098
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
A gelcasting process has been developed to fabricate tubular NiO/YSZ anode-support for solid oxide fuel cells (SOFCs) successfully. The theological behaviors of the ceramic particle suspensions for gelcasting were investigated as a function of the process parameters, such as the amount of pore former, pH value, dispersant concentration, monomer concentration, ball-mill time and solid loading. The sintering shrinkage, microstructure, bending strength and electrical conductivity of the sintered specimens were examined. The tubular Ni/YSZ anode-support obtained under the optimized preparation conditions exhibited a porosity of 39.6%, mean pore size of below 0.9 mu m, 482 s cm(-1) in electrical conductivity at 700 degrees C, and the bending strength of 112.8 MPa, which can well meet the requirements for SOFCs. (c) 2006 Elsevier B.V. All rights reserved.
引用
收藏
页码:217 / 223
页数:7
相关论文
共 50 条
  • [21] Electrochemical and mechanical properties of solid oxide fuel cell Ni/YSZ anode fabricated from NiO/YSZ composite powder
    Sato, Kazuyoshi
    Naito, Makio
    Abe, Hiroya
    JOURNAL OF THE CERAMIC SOCIETY OF JAPAN, 2011, 119 (1395) : 876 - 883
  • [22] The Reduction Process of a NiO/YSZ Anode for Intermediate Temperature Solid Oxide Fuel Cells
    Liu Bin
    Zhang Yun
    Tu Baofeng
    Liu Lin
    Dong Yonglai
    Cheng Mojie
    CHINESE JOURNAL OF CATALYSIS, 2008, 29 (10) : 979 - 986
  • [23] Carbothermal reduction of the YSZ–NiO solid oxide fuel cell anode precursor by carbon-based materials
    E. Arico
    F. Tabuti
    F. C. Fonseca
    D. Z. de Florio
    A. S. Ferlauto
    Journal of Thermal Analysis and Calorimetry, 2009, 97 : 157 - 161
  • [24] Evaluation of Mechanical Strength of NiO–YSZ Anode in Solid Oxide Fuel Cell Based on Small Punch Test
    Sοng M.
    Hu J.
    Jiang W.
    Zhang Y.
    Niu R.
    Tοng J.
    Kuei Suan Jen Hsueh Pao/Journal of the Chinese Ceramic Society, 2024, 52 (01): : 9 - 18
  • [25] Formation of NiO/YSZ functional anode layers of solid oxide fuel cells by magnetron sputtering
    Ionov, I. V.
    Solov'ev, A. A.
    Lebedinskii, A. M.
    Shipilova, A. V.
    Smolyanskii, E. A.
    Koval'chuk, A. N.
    Lauk, A. L.
    RUSSIAN JOURNAL OF ELECTROCHEMISTRY, 2017, 53 (06) : 670 - 676
  • [26] Improvement of the performances of tubular solid oxide fuel cells by optimizing co-sintering temperature of the NiO/YSZ anode-YSZ electrolyte double layers
    Dong, Dehua
    Liu, Mingfei
    Dong, Yingchao
    Lin, Bin
    Yang, Jiakui
    Meng, Guangyao
    JOURNAL OF POWER SOURCES, 2007, 171 (02) : 495 - 498
  • [27] Formation of NiO/YSZ functional anode layers of solid oxide fuel cells by magnetron sputtering
    I. V. Ionov
    A. A. Solov’ev
    A. M. Lebedinskii
    A. V. Shipilova
    E. A. Smolyanskii
    A. N. Koval’chuk
    A. L. Lauk
    Russian Journal of Electrochemistry, 2017, 53 : 670 - 676
  • [28] Redox stable Ni-YSZ anode support in solid oxide fuel cell stack configuration
    Faes, Antonin
    Wuillemin, Zacharie
    Tanasini, Pietro
    Accardo, Nicola
    Van Herle, Jan
    JOURNAL OF POWER SOURCES, 2011, 196 (07) : 3553 - 3558
  • [29] Dense and Low Oxygen Permeability Bilayer Ceramic Interconnect for Tubular Anode-Support Solid Oxide Cells
    Yang, Xin
    Qiu, Peng
    Xu, Nansheng
    Jia, Lichao
    Zhang, Lei Alexander
    Huang, Kevin
    ACS APPLIED ENERGY MATERIALS, 2021, 4 (01): : 341 - 349
  • [30] Operating Characteristics of a Tubular Direct Carbon Fuel Cell Based on a General Anode Support Solid Oxide Fuel Cell
    Yun, Ui-Jin
    Jo, Min-Je
    Lee, Jong-Won
    Lee, Seung-Bok
    Lim, Tak-Hyoung
    Park, Seok-Joo
    Song, Rak-Hyun
    INDUSTRIAL & ENGINEERING CHEMISTRY RESEARCH, 2013, 52 (44) : 15466 - 15471