-functionalized magnetic nanoparticles as an efficient and reusable catalyst for one-pot synthesis of -amino phosphonates

被引:2
|
作者
Hamadi, Hosein [1 ]
Norouzi, Meysam [1 ]
机构
[1] Shahid Chamran Univ Ahvaz, Chem Dept, Fac Sci, Ahvaz, Iran
关键词
Magnetic nanoparticle; N-hydroxy-alpha-amino phosphonate; catalysis; one-pot synthesis; multicomponent reaction; KABACHNIK-FIELDS REACTION; SOLVENT-FREE; ALPHA-AMINOPHOSPHONATES; FACILE SYNTHESIS; ACID; INHIBITORS; ALDEHYDES; HYDROXY; DERIVATIVES; TRIFLATE;
D O I
10.1007/s12039-018-1530-4
中图分类号
O6 [化学];
学科分类号
0703 ;
摘要
Nanomagnetic () was prepared via grafting sulfonic acid on the silica-coated magnetite nanoparticles (MNPs). The catalytic activity of the prepared was probed through the one-pot synthesis of N-hydroxy--amino phosphonates and -amino phosphonates via three-component couplings of phenylhydroxylamine or amines with aldehydes and trialkyl phosphites at room temperature. The synthesized were characterized by XRD, FT-IR, and SEM. The recoverability of the catalyst was achieved by a simple magnetic decantation and reused at least five times without significant degradation in catalytic activity. The catalytic activity of the prepared was probed through the one-pot synthesis of N-hydroxy--amino phosphonates and -amino phosphonates via three-component couplings of phenylhydroxylamine or amines with aldehydes and trialkyl phosphites at room temperature.
引用
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页数:11
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