Xanthan Sulfuric Acid as an Efficient Biodegradable and Recyclable Catalyst for the One-pot Synthesis of α-Amino Phosphonates

被引：32

作者：

Sun, Guo-Ying ^{[1
]}

Hou, Jun-Tao ^{[1
]}

Dou, Jing-Jie ^{[1
]}

Lu, Jun ^{[1
]}

Hou, Yong-Jie ^{[1
]}

Xue, Tuo ^{[1
]}

Zhang, Zhan-Hui ^{[1
]}

机构：

[1] Hebei Normal Univ, Coll Chem & Mat Sci, Shijiazhuang 050016, Peoples R China

来源：

JOURNAL OF THE CHINESE CHEMICAL SOCIETY | 2010年 / 57卷 / 6B期

基金：

中国国家自然科学基金;

关键词：

Xanthan sulfuric acid; alpha-Aminophosphonates; One-pot synthesis; Aldehyde; Amine; Diethylphosphite; Solvent-free; KABACHNIK-FIELDS REACTION; MAGNETIC FE3O4 NANOPARTICLES; 3-COMPONENT SYNTHESIS; REUSABLE CATALYST; SOLVENT; AMINOPHOSPHONATES; DERIVATIVES; ALDEHYDES; CHLORIDE; MULTICOMPONENT;

D O I：

10.1002/jccs.201000194

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

A convenient and efficient procedure for the synthesis of alpha-amino phosphonates by a one-pot, three-component condensation of aldehydes, amine, and diethyl phosphite in the presence of xanthan sulfuric acid as a bio-supported catalyst under solvent-free conditions has been developed. A wide range of a-amino phosphonates have been obtained in high to excellent yields. Furthermore, the catalyst can be recovered simply and reused several times in subsequent reactions.

引用

页码：1315 / 1320

页数：6

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