The selective functionalization of saturated hydrocarbons. Part 46. An investigation of Udenfriend's system under Gif conditions.

被引：2

作者：

Barton, DHR ^{[1
]}

Delanghe, NC ^{[1
]}

机构：

[1] Texas A&M Univ, Dept Chem, College Stn, TX 77842 USA

来源：

TETRAHEDRON | 1998年 / 54卷 / 18期

基金：

美国国家科学基金会;

关键词：

D O I：

10.1016/S0040-4020(98)00163-X

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Under Gif conditions using ascorbic acid as reductant and oxygen as oxidant in pyridine, the selectivity for secondary hydrogen functionalization is exceptional. EDTA (ethylenediamine-tetra-acetic acid) is not needed as a ligand for iron. (C) 1998 Elsevier Science Ltd. All rights reserved.

引用

页码：4471 / 4476

页数：6

共 13 条

[11] FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .4. THE GIF SYSTEM FOR SELECTIVE OXIDATION USING MOLECULAR-OXYGEN
BARTON, DHR
BOIVIN, J
GASTIGER, M
MORZYCKI, J
HAYMOTHERWELL, RS
MOTHERWELL, WB
OZBALIK, N
SCHWARTZENTRUBER, KM
JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 1, 1986, (06): : 947 - 955
[12] The selective functionalization of saturated hydrocarbons.: Part 45.: The effect of lower temperature on the rate and efficiency of formation of oxidized products in the FeIII-FeV and FeII-FeIV manifolds
Barton, DHR
Li, TS
Peralez, E
TETRAHEDRON, 1998, 54 (50) : 15087 - 15096
[13] THE SELECTIVE FUNCTIONALIZATION OF SATURATED-HYDROCARBONS .28. THE ACTIVATION OF BENZYLIC METHYLENE GROUPS UNDER GOAGG(IV) AND GOAGG(V) CONDITIONS
BARTON, DHR
WANG, TL
TETRAHEDRON, 1994, 50 (04) : 1011 - 1032

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