Iron-catalyzed selective reduction of nitroarenes to anilines using organosilanes

被引：222
|
作者：
Junge, Kathrin [1 ]
Wendt, Bianca [1 ]
Shaikh, Nadim [1 ]
Beller, Matthias [1 ]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse EV, D-18059 Rostock, Germany
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 10期
关键词：
BIOMIMETIC TRANSFER HYDROGENATION; CHEMOSELECTIVE HYDROGENATION; ENANTIOSELECTIVE CATALYSIS; PORPHYRIN CATALYSTS; NITRO-COMPOUNDS; KETONES; HYDROSILYLATION; COMPLEXES; CONVENIENT; ALDEHYDES;
D O I：
10.1039/b924228g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The iron-catalyzed reduction of aromatic nitro compounds to the corresponding anilines applying organosilanes is reported. In the presence of FeX2-R3P catalysts a series of nitroarenes is selectively reduced tolerating a wide range of functional groups.
引用
收藏
页码：1769 / 1771
页数：3
相关论文
共 50 条
  • [41] A Facile and Efficient Iron-Catalyzed Reduction of Sulfoxides to Sulfides
    Enthaler, Stephan
    CHEMCATCHEM, 2011, 3 (04) : 666 - 670
  • [42] A Convenient and General Iron-Catalyzed Reduction of Amides to Amines
    Zhou, Shaolin
    Junge, Kathrin
    Addis, Daniele
    Das, Shoubhik
    Beller, Matthias
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (50) : 9507 - 9510
  • [43] Iridium-catalyzed transfer hydrogenation of nitroarenes to anilines
    Chen, Shujie
    Lu, Guoping
    Cai, Chun
    NEW JOURNAL OF CHEMISTRY, 2015, 39 (07) : 5360 - 5365
  • [44] Synthesis of quinolines by iron-catalyzed reaction of anilines with propane-1,3-diol
    R. I. Khusnutdinov
    A. R. Bayguzina
    R. I. Aminov
    Russian Journal of General Chemistry, 2015, 85 : 2725 - 2727
  • [45] Synthesis of Quinolines by Iron-Catalyzed Reaction of Anilines with Propane-1,3-diol
    Khusnutdinov, R. I.
    Bayguzina, A. R.
    Aminov, R. I.
    RUSSIAN JOURNAL OF GENERAL CHEMISTRY, 2015, 85 (12) : 2725 - 2727
  • [46] Highly selective reduction of nitroarenes to anilines catalyzed using MOF-derived hollow Co3S4 in water under ambient conditions
    Xu, Yong
    Lv, Xiao-Jun
    Chen, Yong
    Fu, Wen-Fu
    CATALYSIS COMMUNICATIONS, 2017, 101 : 31 - 35
  • [47] Highly selective reduction of nitroarenes by iron(0) nanoparticles in water
    Dey, Raju
    Mukherjee, Nirmalya
    Ahammed, Sabir
    Ranu, Brindaban C.
    CHEMICAL COMMUNICATIONS, 2012, 48 (64) : 7982 - 7984
  • [48] Heterogeneous Iron-Catalyzed Hydrogenation of Nitroarenes under Water-Gas Shift Reaction Conditions
    Ryabchuk, Pavel
    Junge, Kathrin
    Beller, Matthias
    SYNTHESIS-STUTTGART, 2018, 50 (22): : 4369 - 4376
  • [49] Iron-Catalyzed anti-Selective Carbosilylation of Internal Alkynes
    Iwamoto, Takahiro
    Nishikori, Tatsushi
    Nakagawa, Naohisa
    Takaya, Hikaru
    Nakamura, Masaharu
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2017, 56 (43) : 13298 - 13301
  • [50] A Concise Route to Cyclic Amines from Nitroarenes and Ketoacids under Iron-Catalyzed Hydrosilylation Conditions
    Wu, Jiajun
    Tongdee, Satawat
    Ammaiyappan, Yuvaraj
    Darcel, Christophe
    ADVANCED SYNTHESIS & CATALYSIS, 2021, 363 (15) : 3859 - 3865
12345