Iron-catalyzed selective reduction of nitroarenes to anilines using organosilanes

被引：222
|
作者：
Junge, Kathrin [1 ]
Wendt, Bianca [1 ]
Shaikh, Nadim [1 ]
Beller, Matthias [1 ]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse EV, D-18059 Rostock, Germany
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 10期
关键词：
BIOMIMETIC TRANSFER HYDROGENATION; CHEMOSELECTIVE HYDROGENATION; ENANTIOSELECTIVE CATALYSIS; PORPHYRIN CATALYSTS; NITRO-COMPOUNDS; KETONES; HYDROSILYLATION; COMPLEXES; CONVENIENT; ALDEHYDES;
D O I：
10.1039/b924228g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The iron-catalyzed reduction of aromatic nitro compounds to the corresponding anilines applying organosilanes is reported. In the presence of FeX2-R3P catalysts a series of nitroarenes is selectively reduced tolerating a wide range of functional groups.
引用
收藏
页码：1769 / 1771
页数：3
相关论文
共 50 条
  • [31] Iron-Catalyzed, Markovnikov-Selective Hydroboration of Styrenes
    Chen, Xu
    Cheng, Zhaoyang
    Lu, Zhan
    ORGANIC LETTERS, 2017, 19 (05) : 969 - 971
  • [32] Selective iron-catalyzed transfer hydrogenation of terminal alkynes
    Wienhoefer, Gerrit
    Westerhaus, Felix A.
    Jagadeesh, Rajenahally V.
    Junge, Kathrin
    Junge, Henrik
    Beller, Matthias
    CHEMICAL COMMUNICATIONS, 2012, 48 (40) : 4827 - 4829
  • [33] Iron-Catalyzed Carbonylation: Selective and Efficient Synthesis of Succinimides
    Driller, Katrin Marie
    Klein, Holger
    Jackstell, Ralf
    Beller, Matthias
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 2009, 48 (33) : 6041 - 6044
  • [34] Selective switchable iron-catalyzed hydrosilylation of carboxylic acids
    Castro, Luis C. Misal
    Li, Haoquan
    Sortais, Jean-Baptiste
    Darcel, Christophe
    CHEMICAL COMMUNICATIONS, 2012, 48 (85) : 10514 - 10516
  • [35] Iron-catalyzed selective oxidative arylation of phenols and biphenols
    Vershinin, Vlada
    Dyadyuk, Alina
    Pappo, Doron
    TETRAHEDRON, 2017, 73 (26) : 3660 - 3668
  • [36] Iron-catalyzed reductive cyclization of nitroarenes: Synthesis of aza-heterocycles and DFT calculations
    Christine Tran
    A?cha Abdallah
    Valentin Duchemann
    Guillaume Lefèvre
    Abdallah Hamze
    Chinese Chemical Letters, 2023, 34 (03) : 366 - 370
  • [37] Rapid and inexpensive method for reduction of nitroarenes to anilines
    Desai, DG
    Swami, SS
    Hapase, SB
    SYNTHETIC COMMUNICATIONS, 1999, 29 (06) : 1033 - 1036
  • [38] REDUCTION OF NITROARENES TO ANILINES IN BASIC ALCOHOLIC MEDIA
    PRATO, M
    QUINTILY, U
    SCORRANO, G
    JOURNAL OF THE CHEMICAL SOCIETY-PERKIN TRANSACTIONS 2, 1986, (09): : 1419 - 1424
  • [39] Iron-catalyzed reductive cyclization of nitroarenes: Synthesis of aza-heterocycles and DFT calculations
    Tran, Christine
    Abdallah, Aicha
    Duchemann, Valentin
    Lefevre, Guillaume
    Hamze, Abdallah
    CHINESE CHEMICAL LETTERS, 2023, 34 (03)
  • [40] Iron-catalyzed reduction of carboxylic and carbonic acid derivatives
    Merel, Delphine S.
    Minh Loan Tran Do
    Gaillard, Sylvain
    Dupau, Philippe
    Renaud, Jean-Luc
    COORDINATION CHEMISTRY REVIEWS, 2015, 288 : 50 - 68
12345