Iron-catalyzed selective reduction of nitroarenes to anilines using organosilanes

被引：222
|
作者：
Junge, Kathrin [1 ]
Wendt, Bianca [1 ]
Shaikh, Nadim [1 ]
Beller, Matthias [1 ]
机构：
[1] Univ Rostock, Leibniz Inst Katalyse EV, D-18059 Rostock, Germany
来源：
CHEMICAL COMMUNICATIONS | 2010年 / 46卷 / 10期
关键词：
BIOMIMETIC TRANSFER HYDROGENATION; CHEMOSELECTIVE HYDROGENATION; ENANTIOSELECTIVE CATALYSIS; PORPHYRIN CATALYSTS; NITRO-COMPOUNDS; KETONES; HYDROSILYLATION; COMPLEXES; CONVENIENT; ALDEHYDES;
D O I：
10.1039/b924228g
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
The iron-catalyzed reduction of aromatic nitro compounds to the corresponding anilines applying organosilanes is reported. In the presence of FeX2-R3P catalysts a series of nitroarenes is selectively reduced tolerating a wide range of functional groups.
引用
收藏
页码：1769 / 1771
页数：3
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