Rare earth perfluorooctanoate [RE(PFO)3] catalyzed one-pot Mannich reaction:: three component synthesis of β-amino carbonyl compounds

被引:99
|
作者
Wang, LM [1 ]
Han, JW [1 ]
Sheng, J [1 ]
Tian, H [1 ]
Fan, ZY [1 ]
机构
[1] E China Univ Sci & Technol, Adv Mat Lab, Inst Fine Chem, Shanghai 200237, Peoples R China
关键词
rare earth perfluorooctanoate; Mannich reaction; acetophenone; beta-aminocarbonyl compound; one-pot reaction;
D O I
10.1016/j.catcom.2004.12.009
中图分类号
O64 [物理化学(理论化学)、化学物理学];
学科分类号
070304 ; 081704 ;
摘要
Mannich reaction of acetophenone, aldehydes and aromatic amines catalyzed efficiently by RE(PFO)(3) was described firstly, which carried out smoothly in high yields with three component one-pot method. Furthermore, it was found these catalysts were completely recovered and reused without loss of their catalytic activities and are thus environmentally conscious, and this procedure is a new choice to synthesis beta-aminocarbonyl compounds. (C) 2005 Elsevier B.V. All rights reserved.
引用
收藏
页码:201 / 204
页数:4
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