Synthesis, crystal structure, and fluorescence of a 2-D coordination polymer

被引：23

作者：

Feng, Dan ^{[1
]}

Liu, Shu-Xia ^{[1
]}

Sun, Ping ^{[1
]}

Ma, Feng-Ji ^{[1
]}

Zhang, Wei ^{[1
]}

机构：

[1] NE Normal Univ, Coll Chem, Minist Educ, Key Lab Polyoxometalates Sci, Changchun 130024, Peoples R China

来源：

JOURNAL OF COORDINATION CHEMISTRY | 2010年 / 63卷 / 10期

基金：

美国国家科学基金会;

关键词：

Coordination polymer; Solvothermal condition; Mixed-ligand; Photoluminescent property; HYDROTHERMAL SYNTHESIS; ORGANIC FRAMEWORKS; ZN(II); ACID; ZINC;

D O I：

10.1080/00958972.2010.490293

中图分类号：

O61 [无机化学];

学科分类号：

070301 ; 081704 ;

摘要：

A 2-D coordination polymer with mixed ligands, [Zn2(BDC)(4,4'-bipy) (HCOO)2] (1) (BDC, 1,4-benzenedicarboxylate; 4,4'-bipy, 4,4'-bipyridine), has been synthesized by solvothermal reaction. Compound 1 provides the first coordination polymer structure constructed by bridging BDC, 4,4'-bipy, and formate. Both BDC and 4,4'-bipy link zincs alternatively, resulting in a zigzag coordination chain; adjacent chains are further linked by formates to form an infinite extended 2-D folding screen layer. The synthesis mechanism and fluorescence property are discussed.

引用

页码：1737 / 1743

页数：7

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