Samarium(II) iodide reduction of isoxazolidines

被引：55

作者：

Revuelta, J ^{[1
]}

Cicchi, S ^{[1
]}

Brandi, A ^{[1
]}

机构：

[1] Univ Florence, Dipartimento Chim Organ Ugo Schiff, Polo Sci, I-50019 Sesto Fiorentino, Italy

来源：

TETRAHEDRON LETTERS | 2004年 / 45卷 / 45期

关键词：

samarium iodide; reduction; isoxazolidine;

D O I：

10.1016/j.tetlet.2004.09.050

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

SmI2 was used as reducing agent for the N-O bond cleavage in isoxazolidines. The procedure revealed is general and particularly useful for the transformation of 5-spirocyclopropane isoxazolidines to the corresponding beta-aminocyclopropanols, a troublesome transformation with other known reagents. (C) 2004 Elsevier Ltd. All rights reserved.

引用

页码：8375 / 8377

页数：3

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