Samarium(II) iodide reduction of isoxazolidines

被引：55
|
作者：
Revuelta, J [1 ]
Cicchi, S [1 ]
Brandi, A [1 ]
机构：
[1] Univ Florence, Dipartimento Chim Organ Ugo Schiff, Polo Sci, I-50019 Sesto Fiorentino, Italy
来源：
TETRAHEDRON LETTERS | 2004年 / 45卷 / 45期
关键词：
samarium iodide; reduction; isoxazolidine;
D O I：
10.1016/j.tetlet.2004.09.050
中图分类号：
O62 [有机化学];
学科分类号：
070303 ; 081704 ;
摘要：
SmI2 was used as reducing agent for the N-O bond cleavage in isoxazolidines. The procedure revealed is general and particularly useful for the transformation of 5-spirocyclopropane isoxazolidines to the corresponding beta-aminocyclopropanols, a troublesome transformation with other known reagents. (C) 2004 Elsevier Ltd. All rights reserved.
引用
收藏
页码：8375 / 8377
页数：3
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