Regiodivergent reduction of allylic esters with samarium(II) iodide by tuning ester groups and proton sources

被引:24
|
作者
Yoshida, A
Hanamoto, T
Inanaga, J [1 ]
Mikami, K
机构
[1] Tokyo Inst Technol, Dept Chem Technol, Meguro Ku, Tokyo 152, Japan
[2] Kyushu Univ, Inst Fundamental Res Organ Chem, Higashi Ku, Fukuoka 81281, Japan
关键词
D O I
10.1016/S0040-4039(98)00042-2
中图分类号
O62 [有机化学];
学科分类号
070303 ; 081704 ;
摘要
Samarium(II) iodide reduced allylic esters in the presence or the absence of palladium(0) catalyst to give alpha- and gamma-protonated products in a regiodivergent fashion by tuning ester functionality and proton sources. (C) 1998 Elsevier Science Ltd. All rights reserved.
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页码:1777 / 1780
页数:4
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