Direct borohydride fuel cell using Ni-based composite anodes

被引：114
|
作者：
Ma, Jia [1 ]
Sahai, Yogeshwar [1 ]
Buchheit, Rudolph G. [1 ]
机构：
[1] Ohio State Univ, Dept Mat Sci & Engn, Columbus, OH 43210 USA
来源：
JOURNAL OF POWER SOURCES | 2010年 / 195卷 / 15期
关键词：
Fuel cell; Direct borohydride fuel cell; Nickel-based composite; Oxygen; Hydrogen peroxide; Cell performance; NICKEL FOAM CATHODE; OXIDATION; ELECTROCATALYSTS; PERFORMANCE; OPERATION; ALLOYS; AU;
D O I：
10.1016/j.jpowsour.2010.02.034
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this study, nickel-based composite anode catalysts consisting of Ni with either Pd on carbon or Pt on carbon (the ratio of Ni:Pd or Ni:Pt being 25:1) were prepared for use in direct borohydride fuel cells (DBFCs). Cathode catalysts used were 1 mg cm(-2) Pt/C or Pd electrodeposited on activated carbon cloth. The oxidants were oxygen, oxygen in air, or acidified hydrogen peroxide. Alkaline solution of sodium borohydride was used as fuel in the cell. High power performance has been achieved by DBFC using non-precious metal, Ni-based composite anodes with relatively low anodic loading (e.g., 270 mW cm(-2) for NaBH4/O-2 fuel cell at 60 degrees C, 665 mW cm(-2) for NaBH4/H2O2 fuel cell at 60 degrees C). Effects of temperature, oxidant, and anode catalyst loading on the DBFC performance were investigated. The cell was operated for about 100 h and its performance stability was recorded. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：4709 / 4713
页数：5
相关论文
共 50 条
  • [1] A high performance direct borohydride fuel cell using bipolar interfaces and noble metal-free Ni-based anodes
    Braesch, Guillaume
    Wang, Zhongyang
    Sankarasubramanian, Shrihari
    Oshchepkov, Alexandr G.
    Bonnefont, Antoine
    Savinova, Elena R.
    Ramani, Vijay
    Chatenet, Marian
    [J]. JOURNAL OF MATERIALS CHEMISTRY A, 2020, 8 (39) : 20543 - 20552
  • [2] A high performance direct borohydride fuel cell using bipolar interfaces and noble metal-free Ni-based anodes
    Braesch, Guillaume
    Wang, Zhongyang
    Sankarasubramanian, Shrihari
    Oshchepkov, Alexandr G.
    Bonnefont, Antoine
    Savinova, Elena R.
    Ramani, Vijay
    Chatenet, Marian
    [J]. Journal of Materials Chemistry A, 2020, 8 (39): : 20543 - 20552
  • [3] Redox cycling of Ni-based solid oxide fuel cell anodes: A review
    Sarantaridis, D.
    Atkinson, A.
    [J]. FUEL CELLS, 2007, 7 (03) : 246 - 258
  • [4] Investigation of Ni Foam Effect for Direct Borohydride Fuel Cell
    Celik, C.
    San, F. G. Boyaci
    Sarac, H. I.
    [J]. FUEL CELLS, 2012, 12 (06) : 1027 - 1031
  • [5] The effect of catalyst support on the performance of PtRu in direct borohydride fuel cell anodes
    Lam, Vincent W. S.
    Alfantazi, Akram
    Gyenge, Elod L.
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 2009, 39 (10) : 1763 - 1770
  • [6] The effect of catalyst support on the performance of PtRu in direct borohydride fuel cell anodes
    Vincent W. S. Lam
    Akram Alfantazi
    Előd L. Gyenge
    [J]. Journal of Applied Electrochemistry, 2009, 39 : 1763 - 1770
  • [7] The direct borohydride fuel cell
    Demirci, Umit Bilge
    Boyaci, Fatma Gul
    Sener, Tansel
    Behmenyar, Gamze
    [J]. ACTUALITE CHIMIQUE, 2007, : 19 - 25
  • [8] Electrochemical performance of Ni-based anodes for solid oxide fuel cells
    Presto, S.
    Barbucci, A.
    Carpanese, M. P.
    Viviani, M.
    Marazza, R.
    [J]. JOURNAL OF APPLIED ELECTROCHEMISTRY, 2009, 39 (11) : 2257 - 2264
  • [9] Direct borohydride fuel cell
    Wei Jianliang
    Wang Xianyou
    Yi Siyong
    Dai Chunling
    Li Na
    [J]. PROGRESS IN CHEMISTRY, 2008, 20 (09) : 1427 - 1432
  • [10] Electrochemical performance of Ni-based anodes for solid oxide fuel cells
    S. Presto
    A. Barbucci
    M. P. Carpanese
    M. Viviani
    R. Marazza
    [J]. Journal of Applied Electrochemistry, 2009, 39 : 2257 - 2264
12345