Direct borohydride fuel cell using Ni-based composite anodes

被引：114
|
作者：
Ma, Jia [1 ]
Sahai, Yogeshwar [1 ]
Buchheit, Rudolph G. [1 ]
机构：
[1] Ohio State Univ, Dept Mat Sci & Engn, Columbus, OH 43210 USA
来源：
JOURNAL OF POWER SOURCES | 2010年 / 195卷 / 15期
关键词：
Fuel cell; Direct borohydride fuel cell; Nickel-based composite; Oxygen; Hydrogen peroxide; Cell performance; NICKEL FOAM CATHODE; OXIDATION; ELECTROCATALYSTS; PERFORMANCE; OPERATION; ALLOYS; AU;
D O I：
10.1016/j.jpowsour.2010.02.034
中图分类号：
O64 [物理化学（理论化学）、化学物理学];
学科分类号：
070304 ; 081704 ;
摘要：
In this study, nickel-based composite anode catalysts consisting of Ni with either Pd on carbon or Pt on carbon (the ratio of Ni:Pd or Ni:Pt being 25:1) were prepared for use in direct borohydride fuel cells (DBFCs). Cathode catalysts used were 1 mg cm(-2) Pt/C or Pd electrodeposited on activated carbon cloth. The oxidants were oxygen, oxygen in air, or acidified hydrogen peroxide. Alkaline solution of sodium borohydride was used as fuel in the cell. High power performance has been achieved by DBFC using non-precious metal, Ni-based composite anodes with relatively low anodic loading (e.g., 270 mW cm(-2) for NaBH4/O-2 fuel cell at 60 degrees C, 665 mW cm(-2) for NaBH4/H2O2 fuel cell at 60 degrees C). Effects of temperature, oxidant, and anode catalyst loading on the DBFC performance were investigated. The cell was operated for about 100 h and its performance stability was recorded. (C) 2010 Elsevier B.V. All rights reserved.
引用
收藏
页码：4709 / 4713
页数：5
相关论文
共 50 条
  • [41] Preparation and evaluation of Ni-based anodes with straight open pores for solid oxide fuel cells
    Tian, Yanting
    Guo, Xiang
    Wu, Pingping
    Zhang, Xu
    Nie, Zhongquan
    [J]. JOURNAL OF ALLOYS AND COMPOUNDS, 2020, 817
  • [42] Coke Resistant and Sulfur Tolerant Ni-based Cermet Anodes for Solid Oxide Fuel Cells
    Li, Meng
    Hua, Bin
    Jiang, San Ping
    Li, Jian
    [J]. SOLID OXIDE FUEL CELLS 15 (SOFC-XV), 2017, 78 (01): : 1217 - 1228
  • [43] Composite Anodes with Ni Impregnated LST SSZ for Direct Methane Solid Oxide Fuel Cells
    Liu Ya-Di
    Yuan Chun
    Zhou Yu-Cun
    Zou Jie
    Xin Xian-Shuang
    Wang Shao-Rong
    [J]. JOURNAL OF INORGANIC MATERIALS, 2014, 29 (11) : 1121 - 1126
  • [44] Advancements in Ni-based Catalysts for Direct Urea Fuel Cells: A Comprehensive Review
    Putri, Yulia M. T. A.
    Syauqi, Muhammad I.
    Rahmawati, Isnaini
    Aliyah, Aliyah
    Sanjaya, Afiten R.
    Ivandini, Tribidasari A.
    [J]. CHEMELECTROCHEM, 2024, 11 (05)
  • [45] Direct reforming of biogas on Ni-based SOFC anodes: Modelling of heterogeneous reactions and validation with experiments
    Santarelli, Massimo
    Quesito, Francesco
    Novaresio, Valerio
    Guerra, Cosimo
    Lanzini, Andrea
    Beretta, Davide
    [J]. JOURNAL OF POWER SOURCES, 2013, 242 : 405 - 414
  • [46] Sulfur poisoning of Ni-based anodes for Solid Oxide Fuel Cells in H/C-based fuels
    Niakolas, Dimitrios K.
    [J]. APPLIED CATALYSIS A-GENERAL, 2014, 486 : 123 - 142
  • [47] The Performance of a Direct Borohydride/Peroxide Fuel Cell Using Graphite Felts as Electrodes
    Lee, Heng-Yi
    Hsu, Yi-Hsuan
    Tsai, Po-Hong
    Lee, Jiunn-Yih
    Chen, Yong-Song
    [J]. ENERGIES, 2017, 10 (08):
  • [48] Electrolyte effect on the catalytic performance of Ni-based catalysts for direct internal reforming molten carbonate fuel cell
    Li, ZhenLan
    Devianto, Hary
    Yoon, Sung Pil
    Han, Jonghee
    Lim, Tae-Hoon
    Lee, Ho-In
    [J]. INTERNATIONAL JOURNAL OF HYDROGEN ENERGY, 2010, 35 (23) : 13041 - 13047
  • [49] A high output voltage direct borohydride fuel cell
    Raman, RK
    Choudhury, NA
    Shukla, AK
    [J]. ELECTROCHEMICAL AND SOLID STATE LETTERS, 2004, 7 (12) : A488 - A491
  • [50] The direct borohydride fuel cell for UUV propulsion power
    Lakernan, J. Barry
    Rose, Abigail
    Pointon, Kevin D.
    Browning, Darren J.
    Lovell, Keith V.
    Waring, Susan C.
    Horsfall, Jackie A.
    [J]. JOURNAL OF POWER SOURCES, 2006, 162 (02) : 765 - 772
12345