Investigation of Ni Foam Effect for Direct Borohydride Fuel Cell

被引:19
|
作者
Celik, C. [1 ,2 ]
San, F. G. Boyaci [3 ]
Sarac, H. I. [2 ]
机构
[1] UCL, Ctr Technol CO2, London SW1E 7JE, England
[2] Kocaeli Univ, Dept Mech Engn, TR-41380 Kocaeli, Turkey
[3] TUBITAK Marmara Res Ctr, Energy Inst, TR-41470 Gebze, Kocaeli, Turkey
关键词
Borohydride; Direct Borohydride Fuel Cell; Fuel Cell; Ni Foam; Oxidation; OPERATION CONDITIONS; SODIUM-BOROHYDRIDE; ANODIC-OXIDATION; PERFORMANCE;
D O I
10.1002/fuce.201200002
中图分类号
O646 [电化学、电解、磁化学];
学科分类号
081704 ;
摘要
Ni foam has been used as a substrate for the anode electrocatalyst in our previous works. In this study, the effect of nickel foam as an anode electrode in direct borohydride cells has been investigated under steady state/steady-flow and uniform state/uniform-flow systems, since nickel has catalytic property. Cathode catalyst used has been 0.3?mg?cm2 on PTFE-treated Toray carbon paper. The results have showed that power densities have increased by increasing the temperature. Peak power densities of 5.01 and 9.55?mW?cm2 have been achieved at 25 and 60?degrees C, respectively, for 1.5?mol?dm3 NaBH4. On the other hand, the electrochemical performance has not been significantly different by the sodium borohydride concentration; only a small increase of power density has been observed in steady state/steady-flow system, and only a small decrease of fuel utilization ratio has been obtained in uniform state/uniform-flow systems.
引用
收藏
页码:1027 / 1031
页数:5
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