Multinuclear NMR-spectroscopic characterization of alkylperoxo complexes of molybdenum(VI)

被引：3
|
作者：
Dorosheva, TS
Bryliakov, KP
Talsi, EP [1 ]
机构：
[1] Russian Acad Sci, Siberian Branch, GK Boreskov Inst Catalysis, Novosibirsk 630090, Russia
[2] Novosibirsk State Univ, Dept Nat Sci, Novosibirsk 630090, Russia
来源：
MENDELEEV COMMUNICATIONS | 2003年 / 01期
关键词：
D O I：
10.1070/MC2003v013n01ABEH001636
中图分类号：
O6 [化学];
学科分类号：
0703 ;
摘要：
An alkylperoxo molybdenum(VI) intermediate was identified in the reaction of (BuOOH)-O-t with the 1,2-cyclohexanediolo complex of molybdenum(VI) in CHCl3 using C-13, O-17 and Mo-95 NMR spectroscopy.
引用
收藏
页码：8 / 9
页数：2
相关论文
共 50 条
  • [21] NMR-spectroscopic investigations on the hydrolysis of functional trialkoxysilanes
    Brand, M
    Frings, A
    Jenkner, P
    Lehnert, R
    Metternich, HJ
    Monkiewicz, J
    Schram, J
    ZEITSCHRIFT FUR NATURFORSCHUNG SECTION B-A JOURNAL OF CHEMICAL SCIENCES, 1999, 54 (02): : 155 - 164
  • [22] NMR-SPECTROSCOPIC INVESTIGATIONS OF POTENTIALLY PLANARIZED NONAFULVENES
    CHAI, SY
    BONZLI, P
    NEUENSCHWANDER, M
    HELVETICA CHIMICA ACTA, 1995, 78 (01) : 215 - 230
  • [23] NMR-SPECTROSCOPIC CONFORMATIONAL ANALYSIS OF MENTHYLAMINES AND CARVOMENTHYLAMINES
    FELTKAMP, H
    ANGEWANDTE CHEMIE-INTERNATIONAL EDITION, 1965, 4 (08) : 699 - &
  • [24] C-13 NMR-SPECTROSCOPIC INVESTIGATIONS ON PRECIPITATED POLYANION-POLYCATION-COMPLEXES
    KOTZ, J
    KUNZE, J
    LINOW, KJ
    PHILIPP, B
    POLYMER BULLETIN, 1986, 15 (03) : 247 - 252
  • [25] NMR-SPECTROSCOPIC STUDY ON ISOCOUMARIN AND ISOCARBOSTYRIL DERIVATIVES
    DUDDECK, H
    KAISER, M
    SPECTROCHIMICA ACTA PART A-MOLECULAR AND BIOMOLECULAR SPECTROSCOPY, 1985, 41 (07): : 913 - 924
  • [26] NMR-SPECTROSCOPIC INVESTIGATIONS OF SILYL SUBSTITUTED OLEFINS
    HENGGE, E
    PLETKA, HD
    MONATSHEFTE FUR CHEMIE, 1973, 104 (05): : 1365 - 1371
  • [27] SYNTHESIS AND NMR-SPECTROSCOPIC STUDIES OF SUBSTITUTED CYCLOHEXASILANES
    EIBL, M
    KATZENBEISSER, U
    HENGGE, E
    PHOSPHORUS SULFUR AND SILICON AND THE RELATED ELEMENTS, 1992, 64-5 (1-4): : 221 - 224
  • [28] MONONUCLEAR MIXED OXOSULFIDOMOLYBDATE(VI) COMPLEXES WITH AMINODICARBOXYLIC LIGANDS - SYNTHESIS AND SPECTROSCOPIC CHARACTERIZATION BY MULTINUCLEAR MAGNETIC-RESONANCE SPECTROSCOPY
    DOMENECH, A
    LLOPIS, E
    RAMIREZ, JA
    CERVILLA, A
    INORGANICA CHIMICA ACTA, 1993, 204 (01) : 73 - 78
  • [29] SYNTHESIS AND CHARACTERIZATION OF SOME PEROXO COMPLEXES OF MOLYBDENUM(VI) AND DIOXOURANIUM(VI)
    ISLAM, MS
    ISLAM, MN
    UDDIN, MM
    INDIAN JOURNAL OF CHEMISTRY SECTION A-INORGANIC BIO-INORGANIC PHYSICAL THEORETICAL & ANALYTICAL CHEMISTRY, 1994, 33 (11): : 1028 - 1030
  • [30] Synthesis and characterization of mixed ligand complexes of molybdenum(VI)
    Hussain, Ashaq
    Sheikh, H. N.
    Kalsotra, B. L.
    JOURNAL OF THE INDIAN CHEMICAL SOCIETY, 2006, 83 (06) : 531 - 535
12345