Synthesis and characterization of mixed ligand complexes of molybdenum(VI)

被引：0

作者：

Hussain, Ashaq ^{[1
]}

Sheikh, H. N. ^{[1
]}

Kalsotra, B. L. ^{[1
]}

机构：

[1] Univ Jammu, Dept Chem, Jammu 180006, Jammu & Kashmir, India

来源：

JOURNAL OF THE INDIAN CHEMICAL SOCIETY | 2006年 / 83卷 / 06期

关键词：

mixed ligand complexes; molybdenum(VI); substituted urea;

D O I：

暂无

中图分类号：

O6 [化学];

学科分类号：

0703 ;

摘要：

The mixed ligand complexes of molybdenum(VI) of the type, [MoO2(acac)(2)L] where L = morpholinomethyl urea (MMU), morpholinomethyl thiourea (MMTU), piperidinomethyl urea (PMU), piperidinomethyl thiourea (PMTU), pyrrolidinomethyl urea (PyMU) and pyrrolidinomethyl thiourea (PyMTU) have been prepared by the reaction of [MoO2(acac)(2)] with corresponding ligands in 1 : 1 molar ratio. The complexes have been characterized by various physicochemical techniques such as elemental analysis, molar conductance, IR, electronic spectra, cyclic voltammetry in addition to TGA/DTA studies. Morpholinomethyl urea and related ligands behave as monodentate in the complexes coordinating to molybdenum through carbonyl oxygen or thiocarbonyl sulfur.

引用

页码：531 / 535

页数：5

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