Cyclic Anion-Responsive π-Electronic Molecules That Overcome Energy Losses Induced by Conformation Changes

被引：13

作者：

Kaname, Shunsuke ^{[1
]}

Haketa, Yohei ^{[1
]}

Yasuda, Nobuhiro ^{[2
]}

Maeda, Hiromitsu ^{[1
]}

机构：

[1] Ritsumeikan Univ, Dept Appl Chem, Coll Life Sci, Kusatsu 5258577, Japan

[2] Japan Synchrotron Radiat Res Inst, Res & Utilizat Div, Sayo 6795198, Japan

来源：

ORGANIC LETTERS | 2018年 / 20卷 / 11期

关键词：

BF2; COMPLEXES; SUBSTITUTED DIPYRROLYLDIKETONES; RECEPTOR; DIFFRACTOMETRY;

D O I：

10.1021/acs.orglett.8b01138

中图分类号：

O62 [有机化学];

学科分类号：

070303 ; 081704 ;

摘要：

Preorganized structures suitable for anion binding were prepared by introducing dipyrrolyldiketone BF2 complexes as acyclic anion-responsive pi-electronic molecules into macrocycles. Pyrrole-inverted conformations, which typically present low stability in the case of acyclic derivatives, were obtained by covalent linkages through ring-closing olefin metathesis, exhibiting extremely high affinity for different anions.

引用

页码：3268 / 3272

页数：5

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